Published by John Wiley & Sons, Inc., Hoboken, New Jersey.
Published simultaneously in Canada.
No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning, or otherwise, except as permitted under Section 107 or 108 of the 1976 United States Copyright Act, without either the prior written permission of the Publisher, or authorization through payment of the appropriate per-copy fee to the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, (978) 750-8400, fax (978) 750-4470, or on the web at www.copyright.com. Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, (201) 748-6011, fax (201) 748-6008, or online at http://www.wiley.com/go/permission.
Limit of Liability/Disclaimer of Warranty: While the publisher and author have used their best efforts in preparing this book, they make no representations or warranties with respect to the accuracy or completeness of the contents of this book and specifically disclaim any implied warranties of merchantability or fitness for a particular purpose. No warranty may be created or extended by sales representatives or written sales materials. The advice and strategies contained herein may not be suitable for your situation. You should consult with a professional where appropriate. Neither the publisher nor author shall be liable for any loss of profit or any other commercial damages, including but not limited to special, incidental, consequential, or other damages.
For general information on our other products and services or for technical support, please contact our Customer Care Department within the United States at (800) 762-2974, outside the United States at (317) 572-3993 or fax (317) 572-4002.
Wiley also publishes its books in a variety of electronic formats. Some content that appears in print may not be available in electronic formats. For more information about Wiley products, visit our web site at www.wiley.com.
Library of Congress Cataloging-in-Publication Data is available.
ISBN: 978-1-119-32022-7
ISSN: 0196-6219
Preface
The 13th International Symposium on Solid Oxide Fuel Cells (SOFC): Materials, Science, and Technology and Crystalline Materials for Electrical, Optical and Medical Applications symposium were held during the 40th International Conference and Exposition on Advanced Ceramics and Composites in Daytona Beach, FL, January 24–29, 2016. These symposia provided an international forum for scientists, engineers, and technologists to discuss and exchange state-of-the-art ideas, information, and technology on various aspects of solid oxide fuel cells and crystalline materials for electrical, optical, and medical applications. This CESP issue contains 15 papers submitted by authors of these two symposia for inclusion in the meeting proceedings.
The editors wish to extend their gratitude and appreciation to all the authors for their contributions and cooperation, to all the participants and session chairs for their time and efforts, and to all the reviewers for their useful comments and suggestions. Financial support from The American Ceramic Society is gratefully acknowledged. Thanks are due to the staff of the meetings and publications departments of The American Ceramic Society for their invaluable assistance.
Advice, help and cooperation of the following members of the international organizing committee at various stages were instrumental in making these symposa a great success.
13th International Symposium on SOCFs: Vincenzo Esposito, Tatsumi Ishihara, Ruey-Yi Lee, Nguyen Minh, Prabhakar Singh, Federico Smeacetto, Jeffry Stevenson, Toshio Suzuki, Sascha Kuhn, Scott Barnett, and Kristen Brosnan
We hope that this volume will serve as a valuable reference for the engineers, scientists, researchers and others interested in the materials, science and technology of solid oxide fuel cells and crystalline materials for electronic applications.
Mihails Kusnezoff Fraunhofer IKTS, Germany
Narottam P. Bansal NASA Glenn Research Center, USA
Kiyoshi Shimamura National Institute for Materials Science, Japan
Introduction
This collected proceedings consists of 104 papers that were submitted and approved for the proceedings of the 40th International Conference on Advanced Ceramics and Composites (ICACC), held January 24–29, 2016 in Daytona Beach, Florida. ICACC is the most prominent international meeting in the area of advanced structural, functional, and nanoscopic ceramics, composites, and other emerging ceramic materials and technologies. This prestigious conference has been organized by the Engineering Ceramics Division (ECD) of The American Ceramic Society (ACerS) since 1977. This year’s meeting continued the tradition and added a few grand celebrations to mark its 40th year.
The 40th ICACC hosted more than 1,100 attendees from 42 countries that gave over 900 presentations. The topics ranged from ceramic nanomaterials to structural reliability of ceramic components, which demonstrated the linkage between materials science developments at the atomic level and macro level structural applications. Papers addressed material, model, and component development and investigated the interrelations between the processing, properties, and microstructure of ceramic materials.
The 2016 conference was organized into the following 17 symposia and 5 Focused Sessions:
Symposium 1
Mechanical Behavior and Performance of Ceramics and Composites
Symposium 2
Advanced Ceramic Coatings for Structural, Environmental, and Functional Applications
Symposium 3
13th International Symposium on Solid Oxide Fuel Cells (SOFC): Materials, Science, and Technology
Symposium 4
Armor Ceramics: Challenges and New Developments
Symposium 5
Next Generation Bioceramics and Biocomposites
Symposium 6
Advanced Materials and Technologies for Direct Thermal Energy Conversion and Rechargeable Energy Storage
Symposium 7
10th International Symposium on Nanostructured Materials: Functional Nanomaterials and Thin Films for Sustainable Energy Harvesting, Environmental and Health Applications
Symposium 8
10th International Symposium on Advanced Processing & Manufacturing Technologies for Structural & Multifunctional Materials and Systems
Symposium 9
Porous Ceramics: Novel Developments and Applications
Symposium 10
Virtual Materials (Computational) Design and Ceramic Genome
Symposium 11
Advanced Materials and Innovative Processing ideas for the Production Root Technology
Symposium 12
Materials for Extreme Environments: Ultrahigh Temperature Ceramics (UHTCs) and Nano-laminated Ternary Carbides and Nitrides (MAX Phases)
Symposium 13
Advanced Materials for Sustainable Nuclear Fission and Fusion Energy
Symposium 14
Crystalline Materials for Electrical, Optical and Medical Applications
Focused Session 1
Geopolymers, Chemically Bonded Ceramics, Eco-friendly and Sustainable Materials
Focused Session 2
Advanced Ceramic Materials and Processing for Photonics and Energy
Focused Session 3
Materials Diagnostics and Structural Health Monitoring of Ceramic Components and Systems
Focused Session 4
Additive Manufacturing and 3D Printing Technologies
Focused Session 5
Field Assisted Sintering and Related Phenomena at High Temperatures
Focused Session 6
Hybrid Materials and Processing Technologies
Special Symposium
40th Jubilee Symposium: Engineered Ceramics—Current Status and Future Prospects
Special Symposium
5th Global Young Investigators Forum
Special Symposium
Emerging Technologies Symposium: Carbon Nanostructures and 2D Materials and Composites
The proceedings papers from this conference are published in the below seven issues of the 2016 CESP; Volume 37, Issues 2–7, as listed below.
Mechanical Properties and Performance of Engineering Ceramics and Composites XI, CESP Volume 37, Issue 2 (includes papers from Symposium 1)
Advances in Solid Oxide Fuel Cells and Electronic Ceramics II, CESP Volume 37, Issue 3 (includes papers from Symposia 3 and 14)
Advances in Ceramic Armor, Bioceramics, and Porous Materials, CESP Volume 37, Issue 4 (includes papers from Symposia 4, 5, and 9)
Advanced Processing and Manufacturing Technologies for Nanostructured and Multifunctional Materials III, CESP Volume 37, Issue 5 (includes papers from Symposia 8 and 11 and Focused Sessions 4 and 5)
Ceramic Materials for Energy Applications VI, CESP Volume 37, Issue 6 (includes papers from Symposia 6 and 13 and Focused Session 2)
Developments in Strategic Materials II, CESP Volume 37, Issue 7 (includes papers from Symposia 2, 10, 12, Focused Sessions 1, and the Special Symposia on Carbon).
The organization of the Daytona Beach meeting and the publication of these proceedings were possible thanks to the professional staff of ACerS and the tireless dedication of many ECD members. We would especially like to express our sincere thanks to the symposia organizers, session chairs, presenters and conference attendees, for their efforts and enthusiastic participation in the vibrant and cutting-edge conference.
ACerS and the ECD invite you to attend the 41st International Conference on Advanced Ceramics and Composites (http://www.ceramics.org/icacc2017) January 23–28, 2017 in Daytona Beach, Florida.
To purchase additional CESP issues as well as other ceramic publications, visit the ACerS-Wiley Publications home page at www.wiley.com/go/ceramics.
Manabu Fukushima, National Institute of Advanced Industrial Science and Technology (AIST), Japan
Andrew Gyekenyesi, Ohio Aerospace Institute/NASA Glenn Research Center, USA
Volume Editors August 2016
Solid Oxide Fuel Cells
DEVELOPMENT OF SOFC TECHNOLOGY AT TAIWAN INSTITUTE OF NUCLEAR ENERGY RESEARCH
Ruey-Yi Lee, Yung-Neng Cheng, Tai-Nan Lin, Chang-Sing Hwang, Ning-Yih Hsu, Wen-Tang Hong and Chien-Kuo Liu
Institute of Nuclear Energy Research, Taoyuan, Taiwan, R.O.C.
ABSTRACT
Taiwan Institute of Nuclear Energy Research (INER) has committed to developing the SOFC technology since 2003. Since then, substantial progresses have been made on cell, sealant, stack, reforming catalyst, balance of plant (BOP) components as well as system integration. To date, fabrication processes for both planar anode-supported-cell (ASC) by conventional methods and metal-supported-cell (MSC) by atmospheric plasma spraying have been well established. Numerous stack tests were carried out with consistent and repeatable results. Several thousand hours performance tests were executed to evaluate the reliability and durability of system components. Recently, a compact INER-III SOFC power system has been demonstrated with an electric efficiency higher than 40%.
INTRODUCTION
The merits of Solid Oxide Fuel Cell (SOFC) include high efficiency, module design, insignificant NOx, SOx and particulate emissions, reduced CO2 emissions, fuel flexibility as well as vibration-free operation. Nowadays, the SOFC is considered as an environmentally friendly energy-converting device and an essential bridge from the fossil fuel to the next generation power systems. For the past decade, the INER has imposed critical mass and substantial efforts to develop the core technology of the SOFC technology from powder to power. Elaborative efforts have been made in parallel to the membrane electrode assembly (MEA), stack and power system developments.1–6 Firmed facilities for hardware and software are sequentially set up to move forward the SOFC technology development. A series of MEA and short stack tests have been conducted to evaluate the cell/stack performance for further improvement and to find out the key operational parameters. In 2007, the first home-made MEA with a maximum power density higher than 500 mW/cm2 was fabricated. At the end of 2007, the first 1kW stack with InDec cells inside was assembled and tested with success. In November of 2008, through a close international collaboration between INER and HTceramix SA, over 1000-hour performance test of the HTc’s long stack in the INER’s test facility was carried out with an electric output over 1 kW. A prototype of INER’s first 1-kW SOFC power system with natural gas as fuel was illustrated thermally self-sustaining at the last week of 2011. The system was then transferred to the China Steel Cooperation (CSC) for further in-situ testing. A durability test over 15,000 hours for INER’s ASC cell under a constant current density of 400 mA/cm2 with a degradation rate of about 1%/khr was fulfilled in 2012. A technology transfer on the fabrication processes of the SOFC MEA was signed to a local fine ceramic company in January of 2014. Through the system integration of hot components of the balance of plant, the second generation of INER-II with a system volume reduction of 55% compared to the first prototype was demonstrated and transferred to the China Petroleum Cooperation in 2013. A further system volume reduction of 20% for a compact INER-III power system with satisfactory electric efficiency was achieved in 2015. In this paper, developments of MEA (ASC and MSC), high temperature seals, stack and system at INER are updated.