Contents
Cover
Editorial Board
Title Page
Copyright
Preface to the Series
Contributors to Volume 149
Chapter 1: Quantum Dynamical Resonances in Chemical Reactions: From A + BC to Polyatomic Systems
I. Introduction
II. A Few Basic Concepts
III. Experimental Approaches
IV. The Benchmark F + HD Reaction
V. An Obvious Extension: F + Methane
VI. A Less-Obvious Reaction: Cl + Methane
VII. Summary and Outlook
Acknowledgments
Chapter 2: The Multiscale Coarse-Graining Method
I. Introduction
II. Methodology
III. Results
IV. Conclusion
Acknowledgments
Chapter 3: Molecular Solvation Dynamics from Inelastic X-Ray Scattering Measurements
I. Introduction
II. Review of High-Resolution Inelastic X-Ray Scattering on Liquid Water: Theory and Experiment
III. Green's Function Imaging of Dynamics with Femtosecond Temporal and Angstrom Spatial Resolution
IV. An excluded volume implementation for Green's Function Imaging of Dynamics
V. Conclusions and Outlook
Chapter 4: Polymers Under Confinement
I. Introduction
II. Models of a Polymer Chain
III. Anisotropic Confinement
IV. Confinement in Spherical Cavities
V. Confinement in Cylindrical Cavities
VI. Confinement in Slab-Like Geometries
VII. Conclusions
Acknowledgments
Chapter 5: Computational Studies Of The Properties Of Dna-Linked Nanomaterials
1. Introduction
II. Optical Properties of DNA-Au NPs
III. Melting Properties of DNA-Au NPs
IV. Structural Properties of the Self-Assembled Materials
V. Conformation of DNA
VI. Conclusion
Chapter 6: Nanopores: Single-Molecule Sensors of Nucleic Acid-Based Complexes
I. Introduction
II. DNA Capture and Translocation Processes
III. Probing DNA/Small Molecule Interactions
IV. Nanopore-Based Genomic Profiling Using Sequence-Specific Probes
V. Summary
Author Index
Subject Index
Editorial Board
Moungi G. Bawendi Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts, USA
Kurt Binder Condensed Matter Theory Group, Institut für Physik, Johannes Gutenberg-Universität Mainz, Mainz, Germany
William T. Coffey Department of Electronics and Electrical Engineering, Trinity College, University of Dublin, Dublin, Ireland
Karl F. Freed Department of Chemistry, James Franck Institute, University of Chicago, Chicago, Illinois, USA
Daan Frenkel Department of Chemistry, Trinity College, University of Cambridge, Cambridge, United Kingdom
Pierre Gaspard Center for Nonlinear Phenomena and Complex Systems, Université Libre de Bruxelles, Brussels, Belgium
Martin Gruebele School of Chemical Sciences and Beckman Institute, Director of Center for Biophysics and Computational Biology, University of Illinois at Urbana-Champaign, Urbana, Illinois, USA
Jean-Pierre Hansen Department of Chemistry, University of Cambridge, Cambridge, United Kingdom
Gerhard Hummer, Chief Theoretical Biophysics Section, NIDDK-National Institutes of Health, Bethesda, Maryland, USA
Ronnie Kosloff Department of Physical Chemistry, Institute of Chemistry and Fritz Haber Center for Molecular Dynamics, The Hebrew University of Jerusalem, Israel
Ka Yee Lee Department of Chemistry and The James Franck Institute, The University of Chicago, Chicago, Illinois, USA
Todd J. Martinez Department of Chemistry, Stanford University, Stanford, California, USA
Shaul Mukamel Department of Chemistry, University of California at Irvine, Irvine, California, USA
Jose Onuchic Department of Physics, Co-Director Center for Theoretical Biological Physics, University of California at San Diego, La Jolla, California, USA
Steven Quake Department of Physics, Stanford University, Stanford, California, USA
Mark Ratner Department of Chemistry, Northwestern University, Evanston, Illinois, USA
David Reichmann Department of Chemistry, Columbia University, New York, New York, USA
George Schatz Department of Chemistry, Northwestern University, Evanston, Illinois, USA
Norbert Scherer Department of Chemistry, James Franck Institute, University of Chicago, Chicago, Illinois, USA
Steven J. Sibener Department of Chemistry, James Franck Institute, University of Chicago, Chicago, Illinois, USA
Andrei Tokmakoff Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts, USA
Donald G. Truhlar Department of Chemistry, University of Minnesota, Minneapolis, Minnesota, USA
John C. Tully Department of Chemistry, Yale University, New Haven, Connecticut, USA
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Published simultaneously in Canada
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Preface to the Series
Advances in science often involve initial development of individual specialized fields of study within traditional disciplines, followed by broadening and overlapping, or even merging, of those specialized fields, leading to a blurring of the lines between traditional disciplines. The pace of that blurring has accelerated in the last few decades, and much of the important and exciting research carried out today seeks to synthesize elements from different fields of knowledge. Examples of such research areas include biophysics and studies of nanostructured materials. As the study of the forces that govern the structure and dynamics of molecular systems, chemical physics encompasses these and many other emerging research directions. Unfortunately, the flood of scientific literature has been accompanied by losses in the shared vocabulary and approaches of the traditional disciplines, and there is much pressure from scientific journals to be ever more concise in the descriptions of studies, to the point that much valuable experience, if recorded at all, is hidden in supplements and dissipated with time. These trends in science and publishing make this series, Advances in Chemical Physics, a much needed resource.
The Advances in Chemical Physics is devoted to helping the reader obtain general information about a wide variety of topics in chemical physics, a field that we interpret very broadly. Our intent is to have experts present comprehensive analyses of subjects of interest and to encourage the expression of individual points of view. We hope that this approach to the presentation of an overview of a subject will both stimulate new research and serve as a personalized learning text for beginners in a field.
Stuart A. Rice
Aaron R. Dinner
Contributors to Volume 149
R. H. Coridan, Department of Bioengineering and California NanoSystems Institute, University of California, Los Angeles, CA 90024, USA
One-Sun Lee, Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113, USA
Kopin Liu, Institute of Atomic and Molecular Sciences (IAMS), Academia Sinica, P. O. Box 23-166, Taipei 10617, Taiwan; Department of Physics, National Taiwan University, Taipei 10617, Taiwan; Department of Chemistry, National Tsing Hua University, Hsinchu 30013, Taiwan
Lanyuan Lu, Computation Institute, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439, USA
Amit Meller, Department of Biomedical Engineering, Boston University, Boston, MA 02215, USA
M. Muthukumar, Department of Polymer Science and Engineering, University of Massachusetts, Amherst, MA 01003, USA
George C. Schatz,} {Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113, USA
Gregory A. Voth, Department of Chemistry, James Franck and Computation Institutes, University of Chicago, 5735 S. Ellis Avenue, Chicago, IL 60637, USA
G. C. L. Wong, Department of Bioengineering and California NanoSystems Institute, University of California, Los Angeles, CA 90024, USA