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Edited by
Inamuddin, Rajender Boddula, Mohd Imran Ahamed and Abdullah M. Asiri
This edition first published 2020 by John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, USA and Scrivener Publishing LLC, 100 Cummings Center, Suite 541J, Beverly, MA 01915, USA
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Library of Congress Cataloging-in-Publication Data
Names: Inamuddin, 1980– editor. | Boddula, Rajender, editor. | Ahamed, Mohd Imran, editor. | Asiri, Abdullah M., editor.
Title: Applications of metal–organic frameworks and their derived materials / edited by Inamuddin, Rajender Boddula, Mohd Imran Ahamed, and Abdullah M. Asiri.
Description: Hoboken, NJ : Wiley-Scrivener, 2020. | Includes bibliographical references and index.
Identifiers: LCCN 2020015462 (print) | LCCN 2020015463 (ebook) | ISBN 9781119650980 (cloth) | ISBN 9781119651161 (adobe pdf) | ISBN 9781119650959 (epub)
Subjects: MESH: Metal–Organic Frameworks--chemistry | Nanostructures--chemistry | Biosensing Techniques
Classification: LCC QD411 (print) | LCC QD411 (ebook) | NLM QD 411 | DDC 547/.05--dc23
LC record available at https://lccn.loc.gov/2020015462
LC ebook record available at https://lccn.loc.gov/2020015463
Cover image: Kris Hackerott
Cover design by Russell Richardson
Metal–organic frameworks (MOFs) are porous crystalline polymers constructed by metal sites and organic building blocks. Since the discovery of MOFs in the 1990s, they have received tremendous research attention for various applications due to their high surface area, controllable morphology, tunable chemical properties, and multifunctionalities. These applications include MOFs as precursors and self-sacrificing templates for synthesizing metal oxides, heteroatom-doped carbons, metal-atoms encapsulated carbons, etc. These nanomaterials present new opportunities for versatile applications such as biomedical, energy conversion and storage, catalysis, and environmental remediation, etc. Hence, awareness and knowledge about MOFs and their derived nanomaterials with conceptual understanding are essential for the advanced material community.
Applications of Metal–Organic Frameworks and Their Derived Materials aim to explore down-to-earth applications in fields such as biomedical, environmental, energy, and electronics. This book provides an overview of the structural and fundamental properties, synthesis strategies, and versatile applications of MOFs and their derived nanomaterials. It gives an updated and comprehensive account of the research in the field of MOFs and their derived nanomaterials. This book will be beneficial for graduate and postgraduate students, faculty members, and research and development specialists working in the area of inorganic chemistry and material science, and chemical engineering, as well as industry professionals and nanotechnologists. Based on thematic topics, the book contains the following 14 chapters:
Chapter 1 presents some recent progress in the sensing field of MOFs and their derived materials. Different types of sensors are outlined based on signal transduction mechanism. The present problems and future development of MOFs and their derived materials in sensing field are also reported.
Chapter 2 discusses briefly the principle of piezo/ferroelectrity and the historical developments of MOF materials applied in piezo/ferroelectric applications.
Chapter 3 briefly surveys the fabrication and functionalization strategies of MOFs and their derived materials. The effects of the construction agents, synthesis techniques, synthesis conditions, and synthesis constitutions are discussed.
Chapter 4 focuses on the use of MOFs in membrane transport having immense potential in clinical and theronaustic applications. It also focuses on the recent developments of MOF materials used in clinical and theronaustic applications.
Chapter 5 discusses the introductory idea about the structure, classification, and properties of MOFs. The major part of the chapter discusses the role of MOF as an electrocatalyst for electrochemical sensing as well as in (electro)organic reactions for organic group transformations.
Chapter 6 focuses on the development of MOFs incorporated with ionic liquid (IL) for their potential application as ion conducting composite polymer electrolyte membranes for rechargeable batteries. Interaction of IL ions with metal nodes and organic linkers of MOFs and ion transport dynamics are discussed through XPS, scanning EXAFS, XANES, and dielectric spectroscopy studies.
Chapter 7 elaborates the use of MOF-based catalysts for the synthesis of fine chemicals. It explains the catalytic effect of MOFs and MOF composites in some of the most common reactions, such as oxidation, cycloaddition, esterification, and C–C bond formation, used in the synthesis of fine chemicals.
Chapter 8 discusses unique physiochemical properties of MOF and derived materials and their application as catalysts for various types of hydrogenation reactions. It also covers the exceptional variation and intensity of MOF-based catalyst structures and their selective application in hydrogenation reaction of various compounds.
Chapter 9 discusses the use of MOFs and their derived materials as sorbents in solid phase extraction applications, including miniaturized approaches. These novel materials constitute a powerful alternative to commercial sorbents due to several outstanding properties, thus providing more selective and sensitive analysis of complex samples.
Chapter 10 discusses the medical applications of MOFs as drug carriers of cancer drugs and as photosensitizers in photodynamic therapy. Additionally, the uses of MOFs as antibacterial and antifungal agents are discussed. The mechanisms of antimicrobial action of MOFs are also presented in addition to the advantages of bioMOFs.
Chapter 11 focuses on the general synthesis of MOFs and the adsorptive removal of ibuprofen, diclofenac, macroxen, and oxybenzone using MIL-100 by adopting in silico process.
Chapter 12 discusses the adsorption performance of some MOFs against volatile organic compounds (VOCs), the effect of some key features of MOF to the adsorption performance, the development of MOF composite for improvement of adsorption performance, an analytical method for modeling the adsorption, and factors influencing the adsorption performance.
Chapter 13 discusses the MOF-based materials as an electrocatalyst in diverse applications. Recent developments of MOF in energy and environmental application such as water splitting, hydrogen evolution reaction, oxygen evolution reaction, carbon dioxide reduction, and electrochemical sensing are summarized.
Chapter 14 reviews recent investigations of MOF pristine and MOF composites as photocatalysts for applications of energy (hydrogen production, CO2 conversion), and environment (degradation of organic/inorganic pollutants). MOF composites, including metals, semiconductors, and multicomponent systems are analyzed in terms of preparation methods, properties, and reaction mechanisms involved in the selected photocatalytic reactions.