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Cover
Dedication
Preface
Part I: Carbide, Alkylidyne, Alkylidene, Alkyl, and Alkane Compounds
1. 1 Monocarbide Complexes
2. 2 Terminal and Bridging Methylidyne (CH) and Other Alkylidyne Complexes
3. 3 Terminal and Bridging Methylidene (CH₂) and Other Alkylidene Complexes
4. 4 Methyl Complexes
  1. 4.1 Neutral Monomeric Complexes
  2. 4.2 Cationic and Anionic Monomeric Complexes
  3. 4.3 Bridged Methyl Complexes
5. 5 Methane and Other Alkane Complexes
6. 6 Terminal and Bridged Ethyl Complexes
7. 7 Propyl, Butyl, and Pentyl Complexes
8. 8 Cycloalkyl and Cycloalkane Complexes
9. 9 Saturated Heterometallacycle Complexes
10. 10 Benzyl Complexes
11. 11 Mixed Alkyl and Alkyl–Aryl Complexes
12. 12 Surface Bound Alkyl, Alkane, and Alkyl–Metal Complexes
  1. 12.1 Metal Surfaces
  2. 12.2 Metalloid Surfaces
  3. 12.3 Inorganic Oxide Surfaces
13. 13 Alkyl, Alkylidyne, and Alkylidene Complexes with Other Functional Groups
  1. 13.1 Hydrides
  2. 13.2 Halides and Mixed Halides and Hydrides
  3. 13.3 Pseudohalides
  4. 13.4 Carbonyl and Dinitrogen Complexes
  5. 13.5 Diazomethane (CH₂N═N) and Related Complexes
  6. 13.6 Organic Isocyanides (Isonitriles, R‐N≡C), Organic Nitriles (R‐C≡N), and Iminoacyl Complexes
  7. 13.7 Carbon Dioxide and Carbon Disulfide Complexes
  8. 13.8 Aqua, Hydroxide, Oxide, Peroxide, and Oxyhalide Complexes
  9. 13.9 Hydrogen Sulfide, Mercaptide, Sulfide, and Disulfide Complexes
  10. 13.10 Alkoxide, Organoperoxide, Ether, and Alcohol Complexes
  11. 13.11 Alkylsulfide, Dialkylsulfide, and Methanethiol Complexes
  12. 13.12 Carboxylate, Thiocarboxylate, Dithiocarboxylate, and Xanthate Complexes
  13. 13.13 Formaldehyde, Formyl, Acetaldehyde, Acyl, and Related Complexes
  14. 13.14 Ketone, Ketenyl, and Related Complexes
  15. 13.15 β‐Diketonate and Related Complexes
  16. 13.16 Nitrogen Bases and Miscellaneous Lewis‐Base and Chelating Ligands
14. 14 Complexes with Metal–Metal Bonds
  1. 14.1 Homonuclear Bonds
  2. 14.2 Heteronuclear Bonds
15. 15 Halogenated Alkyl Complexes
  1. 15.1 Main Group Elements
  2. 15.2 Transition and Actinide Elements
16. References
Part II: Noncyclic Carbon‐Clusters and Unsaturated Hydrocarbon Compounds
1. 16 Linear Carbon Cluster Complexes
  1. 16.1 C₂ Complexes
  2. 16.2 C₃ Complexes
  3. 16.3 C₄ Complexes
  4. 16.4 C₅ and Larger Complexes
2. 17 Ethynyl, Ethyne, and Related Complexes
  1. 17.1 Main Group Elements
  2. 17.2 d and f Block Elements
3. 18 Vinyl and Vinylidene Complexes
4. 19 Ethene and Related Monoalkene Complexes
5. 20 Allyl and Related Complexes
6. 21 Allene and Related Complexes
7. 22 Conjugated and Nonconjugated Diolefin and Related Complexes
  1. 22.1 Butadiene and Butatriene Complexes
  2. 22.2 Pentadiene Complexes
  3. 22.3 Hexadiene Complexes
  4. 22.4 Miscellaneous Olefin Complexes
8. References
Part III: Cyclic, Unsaturated Organometallic Compounds
1. 23 Metal Complexes of Fullerenes and Other Nonlinear Carbon Clusters
2. 24 Three‐carbon Rings
3. 25 Four‐carbon Rings
4. 26 Five‐carbon Rings
  1. 26.1 Cyclopentene and Cyclopentyl Complexes
  2. 26.2 1,3‐Cyclopentadiene, Cyclopentadienone, and Related Complexes
  3. 26.3 Anionic Cyclopentadienide Complexes
  4. 26.4 Covalent Cyclopentadienyl Complexes
5. 27 Six‐carbon Rings
  1. 27.1 Cyclohexene Complexes
  2. 27.2 Cyclohexadiene, Cyclohexadienyl, Oxocyclohexadienyl, and Quinone Complexes
  3. 27.3 Neutral, Cationic, and Anionic Phenyl Complexes
  4. 27.4 Phenyl Compounds with Other Functional Groups
  5. 27.5 Phenyl Complexes with Metal–Metal Bonds
  6. 27.6 Ring‐Substituted Phenyl Complexes
  7. 27.7 Perhalogenated Phenyl Complexes
  8. 27.8 Benzene Ring Complexes
  9. 27.9 Ring‐Substituted Benzene Complexes
  10. 27.10 Benzyne Complexes
6. 28 Seven‐carbon Rings
7. 29 Eight‐carbon Rings
8. 30 Nine‐carbon Rings
9. 31 Ten‐carbon Rings
10. 32 Coupled Organic Ring Complexes
11. 33 Fused Organic Ring Complexes
  1. 33.1 Pentalenyl Complexes
  2. 33.2 Indene and Indenyl Complexes
  3. 33.3 Fluorene and Fluorenyl Complexes
  4. 33.4 Indacenyl Complexes
  5. 33.5 Azulene Complexes
  6. 33.6 Naphthalene and Larger Fused Aromatic Ring Complexes
12. 34 Miscellaneous Cyclic Olefin and Mixed Ring Complexes
13. 35 Carboranes and Metallacarboranes
14. 36 Five‐ and Six‐membered Heterocyclic Rings and Their Metal Complexes
15. 37 Unsaturated Metallacycle Rings with Four or More Atoms
16. References
Index
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List of Tables

Chapter 01
1. Table 1.1 Infrared diatomic metal carbide stretching mode assignments (cm⁻¹).
2. Table 1.2 Theoretical and experimental vibrational assignments (cm⁻¹) for nonlinear CM₂ compounds.
3. Table 1.3 Vibrational assignments (cm⁻¹) associated with carbide motion in “butterfly” tetrairon carbide CO clusters of C_2v symmetry at 100 ^°C.^a)
Chapter 02
1. Table 2.1 Vibrational assignments (cm⁻¹) for transition and actinide metal methylidyne complexes.
2. Table 2.2 HREELS vibrational assignments (cm⁻¹) for methylidyne adsorbed on transition metal surfaces.
3. Table 2.3 HREELS vibrational assignments (cm⁻¹) for ethylidyne adsorbed on transition metal surfaces.
Chapter 03
1. Table 3.1 Ar matrix isolation infrared assignments (cm⁻¹) for neutral organometallic d‐block element complexes of methylidene.
2. Table 3.2 Frequency ranges (cm⁻¹) for the CH₂ modes of bridging methylidene groups.
3. Table 3.3 Vibrational assignments (cm⁻¹) for the ethylidene ligand in coordination complexes and on transition metal surfaces.
Chapter 04
1. Table 4.1 Frequency ranges (cm⁻¹) for terminal CH₃ and CD₃ modes.
2. Table 4.2 Activity of the metal–carbon skeletal modes for (CH₃)_nM compounds (n = 1–6) of various symmetries.
3. Table 4.3 Metal–carbon skeletal mode assignments (cm⁻¹) for (CH₃)_nM, (CD₃)_nM (n = 1–6), and other isotopomers.
4. Table 4.4 Metal–carbon skeletal mode assignments (cm⁻¹) for (CH₃)_mMⁿ⁺ complexes.
5. Table 4.5 Vibrational assignments (cm⁻¹) for tetrameric methyllithium and methylsodium and polymeric dimethylberyllium and dimethylmagnesium.
6. Table 4.6 Metal–carbon stretching assignments (cm⁻¹) for [(CH₃)₃Al]₂ and [(CH₃)₃In]₄ and compounds with Li⋯CH₃─M interactions.
Chapter 05
1. Table 5.1 Comparison of the vibrational assignments (cm⁻¹) for methane and methane–metal complexes.^{^a)}
Chapter 06
1. Table 6.1 Frequency ranges (cm⁻¹) for terminal ethyl modes.
2. Table 6.2 Metal–carbon skeletal mode assignments (cm⁻¹) for monomeric organometallic ethyl complexes.
3. Table 6.3 Low‐frequency assignments (cm⁻¹) for Li[(CH₃)₄Al] and Li[(C₂H₅)₄Al].
Chapter 07
1. Table 7.1 Comparison of ν(MC) assignments (cm⁻¹) for organometallic ethyl and the anti and gauche torsional configurations of n‐propyl and n‐butyl compounds.
Chapter 13
1. Table 13.1 Metal–carbon and metal‐hydride/deuteride stretching assignments (cm⁻¹) for metal‐hydrides/deuterides and methyl, methylidene, and methylidyne hydride/deuteride complexes of the main group elements.
2. Table 13.2 Metal‐hydride stretching mode assignments (cm⁻¹) for nonmethyl alkyl complexes of the group 14 and 15 hydrides.
3. Table 13.3 Matrix infrared metal‐hydride and metal–carbon stretching mode assignments (cm⁻¹) for methyl, methylidene, and methylidyne metal‐hydrides of the d and f group elements.
4. Table 13.4 Comparison of the infrared ν(MgC) assignments (cm⁻¹) for (alkyl)₂Mg and alkylMgX (X = F, Cl, Br) complexes.^a)
5. Table 13.5 Metal–carbon and metal‐halide stretching assignments (cm⁻¹) for group 12 halides and alkyl‐group 12 halides.
6. Table 13.6 Boron–carbon and boron–halide stretching assignments (cm⁻¹) for methyl‐ and ethyl‐boron halides.^a)
7. Table 13.7 Skeletal mode assignments (cm⁻¹) for alkyl Al and Ga fluorides.
8. Table 13.8 Skeletal stretching mode assignments (cm⁻¹) for associated R_nMX_3−n (n = 0–2; R = CH₃, C₂H₅; M = Al, Ga, In; X = Cl, Br, I) complexes with bridging halogens.
9. Table 13.9 Metal–carbon and metal‐halide stretching mode assignments (cm⁻¹) for anionic alkyl Al, Ga, In, and Tl halides.
10. Table 13.10 Skeletal mode frequency ranges (cm⁻¹) for methyl and ethyl halide compounds of Si and Ge.
11. Table 13.11 Frequency variations of the metal–carbon and metal‐halide stretching modes (cm⁻¹) for methyl Si, Ge, and Sn halides in different phases.
12. Table 13.12 Skeletal mode assignments (cm⁻¹) for solid methyl Sn fluorides.^a)
13. Table 13.13 The ν(SnF) assignments (cm⁻¹) for solid and vapor alkyl Sn fluorides.^a)
14. Table 13.14 Skeletal mode assignments (cm⁻¹) for neutral alkyl tin chlorides, bromides, and iodides.
15. Table 13.15 Skeletal stretching mode assignments (cm⁻¹) for anionic alkyl Sn halides.
16. Table 13.16 Skeletal mode assignments (cm⁻¹) for alkyl Pb halides.
17. Table 13.17 Skeletal mode assignments (cm⁻¹) for trivalent alkyl‐group 15 halides.
18. Table 13.18 Proposed skeletal structures for known pentavalent methyl‐group 15 halide compounds.
19. Table 13.19 Skeletal mode assignments (cm⁻¹) for tetrahedral, pentavalent methyl‐group 15 halides.
20. Table 13.20 Skeletal mode assignments (cm⁻¹) for trigonal bipyramidal, pentavalent methyl‐group 15 halides.
21. Table 13.21 Skeletal mode assignments (cm⁻¹) for methyl Se and Te halides.
22. Table 13.22 The metal‐skeletal stretching assignments (cm⁻¹) for ground electronic state organo transition and actinide element halide and mixed hydride/halide complexes formed in matrix infrared studies.^a)
23. Table 13.23 Skeletal mode assignments (cm⁻¹) for methyl–gold halide complexes.^a)
24. Table 13.24 Selected vibrational assignments (cm⁻¹) for covalent alkyl organometallic azide complexes.
25. Table 13.25 Selected vibrational assignments (cm⁻¹) for covalent alkyl organometallic isocyanate complexes.
26. Table 13.26 Selected vibrational assignments (cm⁻¹) for alkyl organometallic isothiocyanate and thiocyanate complexes.
27. Table 13.27 Selected vibrational assignments (cm⁻¹) for alkyl organometallic.
28. Table 13.28 Observed and calculated ν(¹³CN) and ν(C¹⁵N) frequency shifts (cm⁻¹) relative to the ν(CN) frequency at 2198 and 2095 cm⁻¹ for vapor samples of (CH₃)₃SiCN and (CH₃)₃SiNC, respectively.^a)
29. Table 13.29 Selected vibrational assignments (cm⁻¹) for covalent alkyl organometallic cyanide and isocyanide complexes.
30. Table 13.30 Matrix infrared assignments (cm⁻¹) dinitrogen complexes of transition metal methylidene.
31. Table 13.31 Vibrational assignments (cm⁻¹) for alkyl organometallic aqua complexes.
32. Table 13.32 Selected vibrational assignment (cm⁻¹) for alkyl organometallic hydroxide complexes.
33. Table 13.33 Calculated and observed frequencies (cm⁻¹) for the ν(MO) modes of (alkyl)₃MO compounds (M = P, As, Sb).
34. Table 13.34 Selected vibrational assignments (cm⁻¹) for methyl and ethyl complexes of phosphoric and arsenic acids and the corresponding anions.
35. Table 13.35 The ν(CH) assignments (cm⁻¹) for (CH₃)₄ReO, (CH₃)₃ReO₂, and CH₃ReO₃.
36. Table 13.36 ν(MS) assignments (cm⁻¹) for several (alkyl)₃MS compounds (M = P, As, Sb).
37. Table 13.37 Selected vibrational assignments (cm⁻¹) for alkyl organometallic alkoxides.
38. Table 13.38 The ν(COC) and ν(MO) assignments (cm⁻¹) for alkyl‐metal ether complexes.
39. Table 13.39 Selected vibrational assignments (cm⁻¹) for alkyl‐metal alkylsulfides.
40. Table 13.40 Characteristic frequencies (cm⁻¹) for alkyl‐metal acetylacetonates with O,O′‐chelated acetylacetonate ligands.
41. Table 13.41 Selected infrared data (cm⁻¹) for the characteristic modes of complexes with η¹ central C³‐bonded and O,O′‐chelated acetylacetonate ligands.
42. Table 13.42 Vibrational assignments (cm⁻¹) for alkyl organometallic ammonia complexes.
43. Table 13.43 Comparison of the ν(MC) assignments (cm⁻¹) for alkyl‐metal complexes with and without coordinated pyridine, 2,2′‐bipyridine or 1,10‐phenanthroline.
44. Table 13.44 Selected vibrational assignments (cm⁻¹) for methyl organometallic nitrates.
Chapter 14
1. Table 14.1 The ν(MM) assignments (cm⁻¹) of (alkyl)_nM₂ complexes.
2. Table 14.2 Skeletal mode assignments (cm⁻¹) for [(CH₃)₃Si]_nM and [(CH₃)₃Sn]_nM complexes.
3. Table 14.3 Group 14 transition element stretching mode assignments (cm⁻¹) for transition metal complexes with trialkyl group 14 element ligands.
Chapter 15
1. Table 15.1 Vibrational assignments (cm⁻¹) for perhalomethyl complexes of the main group elements.
2. Table 15.2 The ν(MX) and ν(MC) assignments (cm⁻¹) for (CF₃)_mMX_n (X = H/D, F, Cl, Br, I) complexes.
3. Table 15.3 Stretching mode assignments (cm⁻¹) for perhalogenated organometallic complexes of the transition and actinide elements.
Chapter 16
1. Table 16.1 The ν(MC) assignments (cm⁻¹) for MC₂ (M = Sc to Co) and MC₃ (M = Sc to Fe) clusters.
2. Table 16.2 The ν(CC) frequencies (cm⁻¹) for μ‐C₄ chains in complexes with different metal oxidation states.
Chapter 17
1. Table 17.1 The ν(C≡C) assignments (cm⁻¹) for alkenyl complexes of the Group 1 elements.
2. Table 17.2 Vibrational assignments (cm⁻¹) for alkynyl compounds of the Groups 14 and 15 elements.
3. Table 17.3 Vibrational assignments (cm⁻¹) for ethynyl complexes of the d and f block elements.
4. Table 17.4 Selected matrix isolation infrared assignments (cm⁻¹) for η²‐C₂H₂M complexes of the transition elements.^a)
5. Table 17.5 HREELS assignments (cm⁻¹) for ethyne adsorbed on transition element surfaces.
6. Table 17.6 The ν(C≡C) assignments (cm⁻¹) for π‐bonded alkyne–metal complexes.
Chapter 18
1. Table 18.1 Frequency ranges (cm⁻¹) for the normal modes of the vinyl group.
2. Table 18.2 Vinyl mode assignments (cm⁻¹) for (CH₂═CH)_nM complexes of Groups 12–16 elements.^a)
3. Table 18.3 Skeletal mode assignments (cm⁻¹) for (CH₂═CH)_nM and (CH₂═CH)_mMX_n (X = H, halogen, alkyl) complexes of Groups 12–16 elements.
4. Table 18.4 Selected stretching mode assignments (cm⁻¹) for vinyl hydride complexes of the transition and actinide elements in Ar matrices.
Chapter 19
1. Table 19.1 Infrared assignments (cm⁻¹) for metal–ethene complexes in an Ar matrix.
2. Table 19.2 Selected HREELS assignments (cm⁻¹) and πσ^a) values calculated for di‐σ‐C₂H₄ adsorbed on transition metal surfaces.
3. Table 19.3 Selected HREELS assignments (cm⁻¹) and πσ^a) values calculated for π‐C₂H₄ adsorbed on transition metal surfaces.
Chapter 20
1. Table 20.1 Vibrational assignments (cm⁻¹) for η¹‐allyl complexes of several group 12, 14, and 14 elements.
2. Table 20.2 Vibrational assignments (cm⁻¹) for the η³‐allyl modes of transition element complexes.^a)
3. Table 20.3 Bands (cm⁻¹) characteristic of η¹ and η³‐allyl and substituted allyl groups in transition element complexes.
4. Table 20.4 Skeletal modes of (η³‐C₃H₅)₂M compounds.
5. Table 20.5 Skeletal modes of (η³‐C₃H₅)₃M complexes.
6. Table 20.6 Skeletal mode assignments (cm⁻¹) for organometallic η³‐allyl complexes of the transition elements.
Chapter 22
1. Table 22.1 Assignments (cm⁻¹) for 1,3‐butadiene and transition element complexes of 1,3‐butadiene.
Chapter 25
1. Table 25.1 Vibrational assignments (cm⁻¹) for liquid η⁴‐C₄H₄Fe(CO)₃.^a)
Chapter 26
1. Table 26.1 Assignments (cm⁻¹) of the infrared active modes for ionic cyclopentadienide complexes.
2. Table 26.2 Description of the vibrational modes for (η⁵‐C₅H₅)₂M complexes with staggered (D_5d) and eclipsed (D_5h) rings.^a)
3. Table 26.3 Skeletal modes and activities for (η⁵‐C₅H₅)₂M complexes with parallel (D_5h) and angular (C_2v) rings.
4. Table 26.4 Assignments (cm⁻¹) of the q‐ and r‐type X‐sensitive modes for various substituted cyclopentadienyl and phenyl compounds.
5. Table 26.5 Assignments (cm⁻¹) for cyclopentadienyl complexes of the earlier group 1 and 2 elements.
6. Table 26.6 Comparison of vibrational data (cm⁻¹) for cyclopentadiene and η¹‐cyclopentadienyl compounds of mercury.^a)
7. Table 26.7 Skeletal mode assignments (cm⁻¹) for η¹‐cyclopentadienyl compounds of mercury.^a)
8. Table 26.8 Cyclopentadienyl mode assignments (cm⁻¹) for (C₅H₅)₂M (M = Ge, Sn, Pb).
9. Table 26.9 Structures, characteristic infrared spectral features, and frequency ranges (cm⁻¹) for the BH₄⁻ group in metal complexes.^a)
10. Table 26.10 Vibrational assignments (cm⁻¹) for covalent (η⁵‐C₅H₅)₂M transition element complexes.^a)
11. Table 26.11 Noncyclopentadienyl mode assignments (cm⁻¹) for η⁵‐C₅H₅V(CO)₄.^a)
12. Table 26.12 Selected infrared noncyclopentadienyl mode assignments (cm⁻¹) for η⁵‐C₅H₅ and η³‐C₅H₅ group 5 CO complexes and substituted CO complexes of with H, η²‐H₂, and η¹‐N₂ ligands.
13. Table 26.13 The noncyclopentadienyl mode assignments (cm⁻¹) for CO and substituted CO η⁵‐cyclopentdienyl group 6 complexes.
14. Table 26.14 Noncyclopentadienyl mode (cm⁻¹) assignments for CO and substituted CO derivatives of η⁵‐cyclopentadienyl group 7 complexes.
15. Table 26.15 The CO stretching assignments (cm⁻¹) for mono‐ and bimetallic cyclopentadienyl CO complexes of Fe, Ru, and Os with terminal, bridging, and semi‐bridging CO ligands.
16. Table 26.16 The infrared ν_a(CO₂) and ν_s(CO₂) assignments (cm⁻¹) and Δν(CO₂) values for η⁵‐C₅H₅ carboxylates of Fe and Ru.
17. Table 26.17 Noncyclopentadienyl mode assignments (cm⁻¹) for C₅H₅NiNO, C₅D₅NiNO, C₅H₅Ni¹⁵NO, and η⁵‐C₅H₅Pt(CH₃)₃.^a)
18. Table 26.18 Description of the local symmetry vibrational modes of cyclopentadienyl and methylcyclopentadienyl rings.^a)
19. Table 26.19 Ring mode assignments (cm⁻¹) for η⁵‐methylcyclopentadienyl complexes.
20. Table 26.20 Noncyclopentadienyl mode assignments (cm⁻¹) for η⁵‐methylcyclopentadienyl complexes.
21. Table 26.21 Infrared ν_a(CO₂) and ν_s(CO₂) assignments (cm⁻¹) and Δν(CO₂) values for η⁵‐(CH₃)₅C₅ carboxylates of Re and Fe.
22. Table 26.22 Characteristic infrared bands (cm⁻¹) of organometallic complexes of pentachlorocyclopentadiene.^a)
Chapter 27
1. Table 27.1 Infrared frequency ranges (cm⁻¹) for the non‐mass‐sensitive modes of organometallic phenyl compounds.^a)
2. Table 27.2 Infrared and Raman X‐sensitive and δ(C₆H₅‐M‐C₆H₅) mode assignments (cm⁻¹) for phenyl compounds of the main group elements.
3. Table 27.3 The ν(MH)/ν(MD) assignments (cm⁻¹) for (C₆H₅)_mMH_n/(C₆H₅)_mMD_n (M = group 14 and group 15 elements) complexes.
4. Table 27.4 The q‐, boron‐halide stretching, and deformation mode assignments (cm⁻¹) for phenyl‐boron halides.
5. Table 27.5 X‐sensitive and metal‐halide mode assignments (cm⁻¹) for neutral phenyl halides of Si, Ge, and Sn.
6. Table 27.6 Lead‐halide stretching mode assignments (cm⁻¹) for neutral phenyl‐lead halides in the solid state and benzene solution.^a)
7. Table 27.7 Metal‐halide stretching mode assignments (cm⁻¹) for phenyl‐group 15 element halides.
8. Table 27.8 Tellurium‐halide stretching mode assignments (cm⁻¹) for neutral and anionic phenyl‐tellurium halides.
9. Table 27.9 Vibrational assignments (cm⁻¹) for the pseudohalide modes of phenyl‐metal pseudohalides.^a)
10. Table 27.10 Metal‐sulfur mode assignments (cm⁻¹) for symmetrical and unsymmetrical hexaphenyl‐di(group 14) sulfides.^a)
11. Table 27.11 The ν(MM′) assignments (cm⁻¹) for main group and transition element complexes of (C₆H₅)₃M (M = Si, Ge, Sn, P, As).
12. Table 27.12 Selected infrared assignments (cm⁻¹) for (C₆F₅)_nM (n = 2–4) compounds of the main group elements.
13. Table 27.13 The ν(M‐ligand) assignments (cm⁻¹) for C₆F₅‐metal hydrides, halides, and oxides.^a)
14. Table 27.14 Vibrational assignments (cm⁻¹) for benzene and the benzene modes of (η⁶‐C₆H₆)₂M complexes.
15. Table 27.15 Metal‐ring skeletal mode assignments (cm⁻¹) for mono and di η⁶‐benzene complexes.
16. Table 27.16 Selected HREELS vibrational assignments (cm⁻¹) of adsorbed benzene on metal surfaces.^a)
Chapter 29
1. Table 29.1 Olefin frequencies (cm⁻¹) for 1,5‐cyclooctadiene and its metal complexes.
2. Table 29.2 Skeletal mode assignments (cm⁻¹) for 1,5‐cyclooctadiene complexes.
3. Table 29.3 Fundamental mode assignments (cm⁻¹) for 1–4‐η⁴‐C₈H₈Fe(CO)₃.^{^a}
4. Table 29.4 Metal‐ring stretching mode assignments (cm⁻¹) for neutral and cationic organometallic complexes of η⁸‐C₈H₈ from ZEKE spectroscopy.
5. Table 29.5 Description of the infrared and Raman active modes for (η⁸‐C₈H₈)₂M complexes of D_8h symmetry.^{^a}
6. Table 29.6 Vibrational data and approximate infrared and Raman assignments (cm⁻¹) for (η⁸‐C₈H₈)₂M (M = lanthanide and actinide elements) complexes.
Chapter 33
1. Table 33.1 Skeletal mode assignments (cm⁻¹) of the THF solution raman spectra of (η¹‐C₉H₇)₂Hg and η¹‐C₉H₇HgX (X = Cl, Br).^a)
2. Table 33.2 Infrared ν(CO) assignments (cm⁻¹) for indene, indenyl, and substituted indene and indenyl carbonyl complexes of Cr, Mo, and W.
Chapter 34
1. Table 34.1 Selected vibrational assignments (cm⁻¹) for norbornadiene and η⁴‐norbornadiene–metal complexes.^a)
Chapter 35
1. Table 35.1 Infrared data (cm⁻¹) for organometallic η⁵‐carborane complexes.
Chapter 36
1. Table 36.1 Selected thiophene and metal–ligand skeletal mode assignments for thiophene gas and complexes with η¹(S) and η⁵ thiophene rings.^a)

List of Illustrations

Chapter 03
1. Figure 3.1 Normal modes of vibration for the bridging methylene group, M─CH₂─M.
Chapter 04
1. Figure 4.1 Normal modes of vibration for covalent CH₃M compounds.
2. Figure 4.2 Frequency variation of the CH₃ modes for different groups of the periodic table.
3. Figure 4.3 Infrared spectrum of (CH₃)₄Si.
4. Figure 4.4 Infrared spectrum (5000–400 cm⁻¹) of solid [(CH₃)₄Sb]⁺I⁻.
5. Figure 4.5 Variation of the Urey–Bradley metal–carbon bond stretching force constant (k_MC) for the isoelectronic series (CH₃)₂Cd, (CH₃)₂In⁺, and (CH₃)₂Sn²⁺ and (CH₃)₂Hg, (CH₃)₂Tl⁺, and (CH₃)₂Pb²⁺.
Chapter 06
1. Figure 6.1 Normal modes of vibration for the C₂MC₂ skeleton of (C₂H₅)₂M compounds with C_2h symmetry.
2. Figure 6.2 Infrared (‐‐‐) and Raman (^___) spectra of (C₂H₅)₄Sn.
Chapter 08
1. Figure 8.1 Infrared (top) and Raman (bottom) spectra of (c‐C₃H₅)₂Hg.
2. Figure 8.2 Infrared (top) and Raman (bottom) spectra of (c‐C₃H₅)₃Ga.
Chapter 11
1. Figure 11.1 Infrared spectra of cyclohexane diluted [(CH₃)₃Al]₂ (‐‐‐) and (i‐C₄H₉)₃Al (^_) and their 2 : 1 and 1 : 2 mixtures that produce the methyl‐bridged dimers [(i‐C₄H₉)₂(CH₃)Al]₂ (···) and [(i‐C₄H₉)(CH₃)₂Al]₂(‐·‐), respectively, through alkyl exchange.
2. Figure 11.2 Raman spectra of undiluted mixtures of [(CH₃)₃Al]₂ and (i‐C₄H₉)₃Al with (CH₃)₃Al/(i‐C₄H₉)₃Al ratios of (a) 6 : 0, (b) 5 : 1, (c) 4 : 2, (d) 3 : 3, and (e) 0 : 6.
Chapter 13
1. Figure 13.1 Group frequency charts for alkyldiboranes.
2. Figure 13.2 Raman spectrum of liquid (a) CH₃AsH₂, (b) CH₃AsD₂, (c) CD₃AsH₂, and (d) CD₃AsD₂ at −190 °C.
3. Figure 13.3 Infrared spectrum of solid films of (a) CH₃AsH₂, (b) CH₃AsD₂, (c) CD₃AsH₂, and (d) CD₃AsD₂ at room temperature.
4. Figure 13.4 Infrared spectra (600–200 cm⁻¹) of (a) (CH₃)₃SbF₂, (b) (CH₃)₃SbCl₂, and (c) (CH₃)₃SbBr₂.
5. Figure 13.5 Raman spectra of (600–100 cm⁻¹) of (a) (CH₃)₃SbF₂, (b) (CH₃)₃SbCl₂, and (c) (CH₃)₃SbBr₂.
6. Figure 13.6 Infrared (top) and Raman (bottom) spectra of [(CH₃)₂AlF]₄.
7. Figure 13.7 Normal modes of vibration of bridged M₂X₆ molecules [883].
8. Figure 13.8 Structures of solid CH₃SnF₃, (CH₃)₂SnF₂, (CH₃)₃SnF, (CH₃)₂SnClF, and CH₃SnCl₂F.
9. Figure 13.9 Correlation of normal modes for (CH₃)₃MCl (M = C, Si, Ge, Sn). Data are for liquid (CH₃)₃SnCl, except for bands at 720 and 780 cm⁻¹ that were from a CS₂ solution.
10. Figure 13.10 Normal modes of vibration for nonlinear M‐XYZ pseudohalide complexes.
11. Figure 13.11 Infrared and Raman spectra of liquid [(CH₃)₂AlN₃]₃ and [(C₂H₅)₂GaN₃]₃ and solid [(C₂H₅)₂TlN₃]₂.
12. Figure 13.12 Infrared ν(C≡N) and ν(Tl‐CN) frequencies in RTl(CN)Y (R = CH₃ or C₂H₅; Y = tropolonate (T), oxinate (Ox) or other carboxylate ligands).
13. Figure 13.13 Infrared spectrum of (CH₃)₃SiCN vapor. Path length = 1.25 m; spectral slit width = 1.3 cm⁻¹; successive vapor pressure = (a) 2 mmHg; (b) 4 mmHg; (c) 12 mmHg; and (d) 2 mmHg.
14. Figure 13.14 Infrared spectra of (a) linear polymethylsiloxanes (first seven spectra) and (b) cyclic dimethylsiloxanes (last six spectra).
15. Figure 13.15 Frequencies and intensities of ν(SiOSi) bands for various polysiloxanes (^: denotes the band partly observed).
16. Figure 13.16 Infrared spectra of (CH₃)₃SnOH as Nujol or hexachlorobutadiene mulls (^___) and CCl₄ solution (‐ ‐ ‐).
17. Figure 13.17 The (a) infrared and (b) Raman spectra of (CH₃)₃PO and the (c) infrared and (d) Raman spectra of (CH₃)₃AsO.
18. Figure 13.18 Temperature dependence of the infrared spectrum of (CH₃)₄As₂S₂ in CCl₄ and 1,1,2,2‐tetrachloroethane at 30 °C (^___), 60 °C (^{. . .}), and 75 °C (‐ ‐ ‐).
19. Figure 13.19 Relationship of the sum of Hammett's constant σ* and H₃C‐O stretching (x) and Sn‐O ring (o) frequencies.
20. Figure 13.20 Infrared (‐ ‐ ‐) and Raman (^___) spectra of (C₂H₅)₃Al·O(C₂H₅)₂.
21. Figure 13.21 The (a) infrared and (b) Raman spectra (cm⁻¹) of liquid CH₃HgSCH₃.
22. Figure 13.22 Infrared spectra of methylacetoxysilanes.
23. Figure 13.23 Infrared (top) and Raman (bottom) spectra of (C₂H₅)₂InOSCCH₃ that were incorrectly attributed to (C₂H₅)₂GaOSCCH₃ in Ref. [1602].
24. Figure 13.24 Raman (a) and infrared spectra (b) of (CH₃)₂Ga(acac).
25. Figure 13.25 Infrared spectra of sodium dichloro(γ‐acetylacetonato)platinum(II) dehydrate and its d₁ and d₇ isotopomers.
26. Figure 13.26 (a) Nujol mull infrared spectrum of [(CH₃)₃Pt(NH₃)₃]Cl and (b) water solution Raman spectrum of [(CH₃)₃Pt(NH₃)₃]Cl. The x shows Nujol bands in the infrared spectrum and bands from Hg in the Raman spectrum.
27. Figure 13.27 Raman difference spectra: (a) 50 mM uridine + 50 mM CH₃HgClO₄, (b) 50 mM uridine (both solutions 0.1 M in NaClO₄), and (c) difference spectrum (A–B). Solution pH = 7. Scan conditions: 0.25 A intervals, 10 seconds counting time.
28. Figure 13.28 The infrared spectra (Nujol mull) of the (1) bis(trimethyltin)sulfate methanol adduct and (2) bis(trimethyltin)sulfate.
29. Figure 13.29 The infrared spectra of 0.25% (CH₃)₃SbSO₄ in a KBr pellet (^___) and a sample after exposure to air at 40% humidity for 45 min (‐ ‐ ‐).
30. Figure 13.30 Infrared (top) and Raman (bottom) spectra of [(C₂H₅)₂GaSO₂C₂H₅]₂.
Chapter 14
1. Figure 14.1 Raman active skeletal modes for (CH₃)₆M₂ (M = Si, Ge, Sn, Pb).
2. Figure 14.2 The ν(SiSi) modes for the anti and gauche conformers of n‐Si₄(CH₃)₁₀.
3. Figure 14.3 The infrared spectra (140–300 cm⁻¹) of (CH₃)_3−nSnCl_nMo(CO)₃C₅H₅ (n = 0–3). The shaded regions indicate the ν(SnMo) mode [2074].
Chapter 15
1. Figure 15.1 The (a) gas‐phase infrared and (b) liquid‐phase Raman spectra of (CF₃)₃As [2113].
2. Figure 15.2 Infrared spectra (940–860 cm⁻¹ and 680–440 cm⁻¹) after co‐deposition of ⁶Li, Na, K, and Cs atoms at 14 K with CCl₄ at high dilutions in an Ar matrix [2196].
Chapter 17
1. Figure 17.1 The (a) CCl₄ solution and (b) solid‐state infrared spectra of (CH₃C≡C)₃As.
2. Figure 17.2 Multiple infrared bands in the ν(C≡C) region of [η⁵‐(CH₃)₅C₅](dppe)Ru[C≡C‐4‐bpy] due to three conformational minima.
3. Figure 17.3 Structure of solid C₆H₅C≡CCuP(CH₃)₃.
4. Figure 17.4 Structure of solid C₆H₅C≡CAgP(CH₃)₃.
Chapter 18
1. Figure 18.1 The (a) infrared and (b) Raman spectra of liquid (CH₂═CH₂)₄Si.
Chapter 19
1. Figure 19.1 Infrared spectrum of Zeise’s salt (4000–33 cm⁻¹).
2. Figure 19.2 Raman spectrum (1700–100 cm⁻¹) of a water solution of K[(CH₂═CHCH₃)PtCl₃]·H₂O at 48 °C.
3. Figure 19.3 The ν(C═C) and δ_s(CH₂) assignments for ethene‐d₀, ethene‐d₄, and the metal complexes of these olefins.
4. Figure 19.4 The RAIRS spectra of ethene on a Pd(111) surface during transformation from the di‐σ‐bonded to the π‐bonded species as H₂ saturation ((H)Θ) increases from zero to one.
Chapter 20
1. Figure 20.1 The (a) infrared and (b) Raman spectra of liquid (CH₂═CHCH₂)₄Si.
2. Figure 20.2 Infrared spectra of liquid η³‐C₃H₅Fe(CO)₂NO (^___) and η³‐C₃D₅Fe(CO)₂NO (‐ ‐ ‐).
3. Figure 20.3 Skeletal modes of the η³‐C₃H₅ unit.
Chapter 22
1. Figure 22.1 Raman spectrum of liquid C₄H₆Fe(CO)₃.
2. Figure 22.2 Infrared spectra of (a) K₂[C₄H₆(PtCl₃)₂] and (b) C₄H₆Fe(CO)₃.
3. Figure 22.3 Infrared spectra of (a) 1,9‐decadiene and of (b) C₁₀H₁₈AgClO₄ as a Nujol mull.
Chapter 25
1. Figure 25.1 KBr pellet infrared spectra of (a) {[(C₆H₅)₄C₄]PtCl₂}_n and (b) {[(C₆H₅)₄C₄]PtI₂}₂.
2. Figure 25.2 KBr pellet infrared spectrum of [(C₆H₅)₄C₄OCH₃PtCl]₂.
Chapter 26
1. Figure 26.1 Normal modes of vibration for the cyclopentadienide anion and their vibrational activity.
2. Figure 26.2 KBr pellet infrared spectrum of C₅H₅K.
3. Figure 26.3 KBr pellet infrared spectrum of (η¹‐C₅H₅)₂Hg.
4. Figure 26.4 Infrared spectrum of (η⁵‐C₅H₅)₂Fe as a KBr pellet.
5. Figure 26.5 Skeletal mode vibrations for (η⁵‐C₅H₅)₂M complexes.
6. Figure 26.6 The molecular structure of (C₅H₅)₃In viewed down the a‐axis.
7. Figure 26.7 The hexachloro‐1,3‐butadiene (1450–1325 cm⁻¹) and Nujol mull (1325–750 cm⁻¹) infrared spectra of (a) (η⁵‐C₅H₅)₂Fe and (b) η⁵‐C₅H₅Fe(C₅H₄HgCl).
8. Figure 26.8 Infrared spectra of (a) solid (C₅H₅)₂Be and (b) (C₅H₅)₂Be vapor.
9. Figure 26.9 Infrared spectrum of C₅H₅Sn(CH₃)₃ (4000–1200 cm⁻¹).
10. Figure 26.10 Nujol mull infrared spectrum (1325–600 cm⁻¹) of [(C₅H₅)(C₅H₄)TiH]₂.
11. Figure 26.11 The infrared spectra of (a) (η⁵‐C₅H₅)₂ZrCl₂ (Nujol), (b) (η⁵‐C₅H₅)₂Zr(H)BH₄ in Nujol, (c) (η⁵‐C₅H₅)₂Zr(BH₄)₂ (Nujol), (d) Al(BH₄)₃ (vapor), (e) (η⁵‐C₅H₅)₂TiBH₄ (Nujol), and (f) (η⁵‐C₅H₅)₂TiCl₂ (Nujol), where the sharp bands marked x are due to Nujol, and the infrared spectra in the BH stretching region of (g) (η⁵‐C₅H₅)₂Zr(H)BH₄, (h) (η⁵‐C₅H₅)₂Zr(BH₄)₂, and (i) (η⁵‐C₅H₅)₂TiBH₄ in benzene solutions.
12. Figure 26.12 Infrared spectra of (a) (η⁵‐C₅H₅)₂TiCl₂ and (b) (η⁵‐C₅D₅)₂TiCl₂.
13. Figure 26.13 Nujol mull infrared spectra (650–50 cm⁻¹) of (a) (η⁵‐C₅H₅)₂TiF₂, (b) (η⁵‐C₅H₅)₂TiCl₂, (c) (η⁵‐C₅H₅)₂TiBr₂, and (d) (η⁵‐C₅H₅)₂TiI₂.
14. Figure 26.14 Infrared spectra of (η⁵‐C₅H₅)₂Ti(O₂CCH₃) (a), η⁵‐C₅H₅Ti(O₂CCH₃)₂ (b), and (η⁵‐C₅H₅)₂Ti(O₂CCH₃)₂ (c) [345]. The shaded bands are from the ν(C─O) mode.
15. Figure 26.15 Infrared ν(CO) spectrum of [η⁵‐C₅H₅Cr(CO)₃]₂ (KBr pellet).
16. Figure 26.16 Infrared ν(CO) spectrum of [(C₅H₅Cr(CO)₃]₂Hg (KI pellet).
17. Figure 26.17 Infrared ν(CO) spectra for [η⁵‐C₅H₅Fe(CO)₂]₂[(i‐C₄H₉)₃Al]₂. Iron dimer concentration = 2.4 × 10⁻³ M: (a) parent Fe complex, (b) Lewis acid concentration, 6.45 × 10⁻³ M; the primary species are [η⁵‐C₅H₅Fe(CO)₂]₂ and its 1 : 1 adduct, (c) Lewis acid concentration, 7.48 × 10⁻³ M; the primary species are the 1 : 1 and 1 : 2 adducts, (d) Lewis acid concentration,1.46 × 10⁻² M; the primary species is the 1 : 2 adduct.
18. Figure 26.18 Infrared spectra of (a) (η⁵‐CH₃C₅H₄)₂TiCl₂ and (b) (η⁵‐CD₃C₅D₄)₂TiCl₂. The ¹H NMR spectrum of the latter compound shows 10% deuteration of the methyl and full deuteration of the ring hydrogens.
19. Figure 26.19 Infrared spectra (Nujol mull) of [η⁵‐(CH₃)₅C₅]₂ScCH₃ and [η⁵‐(CH₃)₅C₅]₂Sc(C₂H₅).
Chapter 27
1. Figure 27.1 The X‐sensitive modes for a monosubstituted benzene ring.
2. Figure 27.2 KBr pellet infrared spectrum of (C₆H₅)₄Sn.
3. Figure 27.3 Raman spectrum of solid (C₆H₅)₄Ge.
4. Figure 27.4 The benzene solution Raman (a–d) and infrared (e–h) spectra of (C₆H₅)₃P, (C₆H₅)₃As, (C₆H₅)₃Sb, and (C₆H₅)₃Bi.
5. Figure 27.5 Infrared spectra of (a) [2,4,6‐(CH₃)₃C₆H₃]Tl(O₃CCF₃)₂ and (b) [2,4,6‐(CH₃)₃C₆H₃]₂TlO₂CCF₃.
6. Figure 27.6 The CHCl₃ solution infrared spectrum of (C₆F₅)₃B.
7. Figure 27.7 Infrared spectrum of crystalline (η⁶‐C₆H₆)₂Cr as a (a) KBr pellet, (b) Hostaflon oil (2–7.5 μm), and Nujol suspension.
8. Figure 27.8 Infrared spectrum of C₆H₆AgAlCl₄ at −180 °C.
9. Figure 27.9 Correlation between the A₁ ν(CO) frequencies for [η⁶‐(CH₃)_nC₆H_6−nMn(CO)₃]I₃ (n = 0–6) and the number of CH₃ groups on the benzene ring.
Chapter 29
1. Figure 29.1 Infrared spectra of (a) 1,5‐C₈H₁₂ (liquid), (b) (1,5‐C₈H₁₂Ag)BF₄, and (c) (1,5‐C₈H₁₂CuCl)₂.
2. Figure 29.2 Raman spectra of (a) liquid 1,5‐C₈H₁₂, (b) (1,5‐C₈H₁₂Ag)BF₄, and (c) (1,5‐C₈H₁₂CuCl)₂.
3. Figure 29.3 Metal–olefin skeletal modes for 1,5‐cyclooctadiene complexes.
4. Figure 29.4 KBr disc infrared spectrum of (η⁸‐C₈H₈)₂Th.
5. Figure 29.5 Raman spectrum of (η⁸‐C₈H₈)₂Th.
Chapter 33
1. Figure 33.1 The hexachlorobutadiene mull infrared spectra of (a) η¹‐C₉H₇HgCl and (b) η⁵‐C₅H₅Fe(CO)₂(η¹‐C₉H₇) in the CH stretching region.
2. Figure 33.2 Infrared spectra (1000–400 cm⁻¹) of (a) η¹‐C₉H₇HgCl and (b) the corresponding derivative that was deuterated at the C1 and C3 atoms.
3. Figure 33.3 Nujol mull infrared spectra of (a) (η⁵‐C₉H₇)₂TiCl₂ and (b) (η⁵‐C₉H₇)₂ZrCl₂.
Chapter 36
1. Figure 36.1 The KBr pellet infrared spectra of azaferrocene (‐ ‐ ‐) and ferrocene (^{. . .}).

Vibrational Spectra of Organometallics

Theoretical and Experimental Data

Copyright

Preface

Part I

Carbide, Alkylidyne, Alkylidene, Alkyl, and Alkane Compounds