Details

Organic Reactions, Volume 100


Organic Reactions, Volume 100


Organic Reactions 1. Aufl.

von: Scott E. Denmark

299,99 €

Verlag: Wiley
Format: PDF
Veröffentl.: 17.10.2019
ISBN/EAN: 9781119570400
Sprache: englisch
Anzahl Seiten: 1136

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Beschreibungen

Written by a "who is who" of leading organic chemists, this anniversary volume represent the Organic Reactions editors' choice of the most important, ground-breaking and versatile reactions in current organic synthesis. The 15 reaction types selected for this volume include reactions for carbon-carbon bond formation, cross-coupling reactions, hydro- and halofunctionalizations, among many others.<br> In line with the successful recipe of the series, each chapter is focused on a single reaction, discussing its mechanism and stereochemistry, scope and limitations, applications to synthesis, comparison with other methods, and experimental procedures. Each chapter concludes with a tabular survey of selected key application examples, complete with reported reaction conditions and yields, to serve as a quick reference guide for synthesis planning.
<p>1. The Negishi Cross-Coupling Reaction 1<br /> <i>Colin Diner and Michael G. Organ</i></p> <p>2. Generation and Trapping of Functionalized Aryl- and Heteroarylmagnesium and -Zinc Compounds 63<br /> <i>Ferdinand H. Lutter, Maximilian S. Hofmayer, Jeffrey M. Hammann, Vladimir Malakhov, and Paul Knochel</i></p> <p>3. Copper-Catalyzed, Enantioselective Hydrofunctionalization of Alkenes 121<br /> <i>Haoxuan Wang and Stephen L. Buchwald</i></p> <p>4. The Catalytic, Enantioselective Favorskii Reaction: in Situ Formation of Metal Alkynylides and Their Additions to Aldehydes 207<br /> <i>Yeshua Sempere and Erick M. Carreira</i></p> <p>5. Enantioselective Lithiation–Substitution of Nitrogen-Containing Heterocycles 255<br /> <i>Kevin Kasten, Nico Seling, and Peter O’Brien</i></p> <p>6. Catalytic, Enantioselective, Transfer Hydrogenation 329<br /> <i>Masahiro Yoshimura and Masato Kitamura</i></p> <p>7. Hydrofunctionalization of Alkenes by Hydrogen-Atom Transfer 383<br /> <i>Ryan A. Shenvi, Jeishla L. M. Matos, and Samantha A. Green</i></p> <p>8. Carbon–Carbon Bond Formation by Metallaphotoredox Catalysis 471<br /> <i>Eric D. Nacsa and David W. C. MacMillan</i></p> <p>9. Suzuki–Miyaura Cross-Coupling 547<br /> <i>Alexander B. Pagett and Guy C. Lloyd-Jones</i></p> <p>10. <i>ortho</i>-Directed C–H Alkylation of Substituted Benzenes 621<br /> <i>Yusuke Ano and Naoto Chatani </i></p> <p>11. Catalytic, Enantioselective, C–H Functionalization to Form Carbon–Carbon Bonds 671<br /> <i>Qing-Feng Wu, Gang Chen, Jian He, and Jin-Quan Yu</i></p> <p>12. Catalytic, Enantioselective Fluorination Reactions 749<br /> <i>Richard T. Thornbury and F. Dean Toste</i></p> <p>13. Catalyst-Controlled Glycosylation 801<br /> <i>Samuel M. Levi and Eric N. Jacobsen</i></p> <p>14. Palladium-Catalyzed Amination of Aryl Halides 853<br /> <i>John F. Hartwig, Kevin H. Shaughnessy, Shashank Shekhar, and Rebecca A. Green</i></p> <p>15. Catalytic, Enantioselective, Copper–Boryl Additions to Alkenes 959<br /> <i>Amir H. Hoveyda, Ming Joo Koh, Kyunga Lee, and Jaehee Lee</i></p> <p>Cumulative Chapter Titles by Volume 1057</p> <p>Author Index, Volumes 1–100 1075</p> <p>Chapter and Topic Index, Volumes 1–100 1083</p>
<p><b>SCOTT E. DENMARK</b> is the Reynold C. Fuson Professor of Chemistry at the University of Illinois at Urbana-Champaign. He has pioneered the concept of chiral Lewis base activation of Lewis acids for catalysis in main group synthetic organic chemistry. His group has also developed palladium-catalyzed cross-couplings with organofunctional silicon compounds. He has won a number of honors including the Pedler and Robert Robinson Medals, the Aldrich Award for Creative Work in Synthetic Organic Chemistry and the Prelog Medal. He was a founding editor of the Encyclopedia of Reagents for Organic Synthesis and served as Editor in Chief of Organic Reactions from 2008 to 2018. He is a member of the American Academy of Arts and Sciences and the National Academy of Sciences.</p>
<p><i>With contributions by</i> <ul> <p>Colin Diner and Michael G. Organ <p>Paul Knochel, Ferdinand H. Lutter, Maximilian S. Hofmayer, Jeffrey M. Hammann, and Vladimir Malakhov <p>Haoxuan Wang and Stephen L. Buchwald <p>Yeshua Sempere and Erick M. Carreira <p>Kevin Kasten, Nico Seling, and Peter O'Brien <p>Masahiro Yoshimura and Masato Kitamura <p>Ryan A. Shenvi, Jeishla L. M. Matos, and Samantha A. Green <p>Eric D. Nacsa and David W. C. MacMillan <p>Alexander B. Pagett and Guy C. Lloyd-Jones <p>Yusuke Ano and Naoto Chatani <p>Qing-Feng Wu, Gang Chen, Jian He, and Jin-Quan Yu <p>Richard T. Thornbury and F. Dean Toste <p>Samuel M. Levi and Eric N. Jacobsen <p>John F. Hartwig, Kevin H. Shaughnessy, Shashank Shekhar, and Rebecca A. Green <p>Amir H. Hoveyda, Ming Joo Koh, Kyunga Lee, and Jaehee Lee </ul>

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