Details

<p>Preface xi</p> <p><b>Part I Carbide, Alkylidyne, Alkylidene, Alkyl, and Alkane Compounds 1</b></p> <p><b>1 Monocarbide Complexes 3</b></p> <p><b>2 Terminal and Bridging Methylidyne (CH) and Other Alkylidyne Complexes 9</b></p> <p><b>3 Terminal and Bridging Methylidene (CH₂) and Other Alkylidene Complexes 13</b></p> <p><b>4 Methyl Complexes 21</b></p> <p>4.1 Neutral Monomeric Complexes 21</p> <p>4.2 Cationic and Anionic Monomeric Complexes 29</p> <p>4.3 Bridged Methyl Complexes 33</p> <p><b>5 Methane and Other Alkane Complexes 37</b></p> <p><b>6 Terminal and Bridged Ethyl Complexes 43</b></p> <p><b>7 Propyl, Butyl, and Pentyl Complexes 49</b></p> <p><b>8 Cycloalkyl and Cycloalkane Complexes 53</b></p> <p><b>9 Saturated Heterometallacycle Complexes 55</b></p> <p><b>10 Benzyl Complexes 59</b></p> <p><b>11 Mixed Alkyl and Alkyl–Aryl Complexes 61</b></p> <p><b>12 Surface Bound Alkyl, Alkane, and Alkyl–Metal Complexes 63</b></p> <p>12.1 Metal Surfaces 63</p> <p>12.2 Metalloid Surfaces 65</p> <p>12.3 Inorganic Oxide Surfaces 66</p> <p><b>13 Alkyl, Alkylidyne, and Alkylidene Complexes with Other Functional Groups 69</b></p> <p>13.1 Hydrides 69</p> <p>13.2 Halides and Mixed Halides and Hydrides 84</p> <p>13.3 Pseudohalides 120</p> <p>13.4 Carbonyl and Dinitrogen Complexes 135</p> <p>13.5 Diazomethane (CH₂N⁺=N⁻) and Related Complexes 139</p> <p>13.6 Organic Isocyanides (Isonitriles, R‐N≡C), Organic Nitriles (R‐C≡N) and Iminoacyl Complexes 139</p> <p>13.7 Carbon Dioxide and Carbon Disulfide Complexes 141</p> <p>13.8 Aqua, Hydroxide, Oxide, Peroxide, and Oxyhalide Complexes 146</p> <p>13.9 Hydrogen Sulfide, Mercaptide, Sulfide, and Disulfide Complexes 161</p> <p>13.10 Alkoxide, Organoperoxide, Ether, and Alcohol Complexes 164</p> <p>13.11 Alkylsulfide, Dialkylsulfide, and Methanethiol Complexes 171</p> <p>13.12 Carboxylate, Thiocarboxylate, Dithiocarboxylate, and Xanthate Complexes 173</p> <p>13.13 Formaldehyde, Formyl, Acetaldehyde, Acyl, and Related Complexes 180</p> <p>13.14 Ketone, Ketenyl, and Related Complexes 187</p> <p>13.15 β‐Diketonate and Related Complexes 190</p> <p>13.16 Nitrogen Bases and Miscellaneous Lewis‐Base and Chelating Ligands 195</p> <p><b>14 Complexes with Metal–Metal Bonds 215</b></p> <p>14.1 Homonuclear Bonds 215</p> <p>14.2 Heteronuclear Bonds 219</p> <p><b>15 Halogenated Alkyl Complexes 225</b></p> <p>15.1 Main Group Elements 225</p> <p>15.2 Transition and Actinide Elements 234</p> <p><b>Part I References 241</b></p> <p><b>Part II Noncyclic Carbon-Clusters and Unsaturated Hydrocarbon Compounds 299</b></p> <p><b>16 Linear Carbon Cluster Complexes 301</b></p> <p>16.1 C₂ Complexes 301</p> <p>16.2 C₃ Complexes 304</p> <p>16.3 C₄ Complexes 304</p> <p>16.4 C₅ and Larger Complexes 305</p> <p><b>17 Ethynyl, Ethyne, and Related Complexes 309</b></p> <p>17.1 Main Group Elements 309</p> <p>17.2 d and f Block Elements 319</p> <p><b>18 Vinyl and Vinylidene Complexes 343</b></p> <p><b>19 Ethene and Related Monoalkene Complexes 355</b></p> <p><b>20 Allyl and Related Complexes 371</b></p> <p><b>21 Allene and Related Complexes 387</b></p> <p><b>22 Conjugated and Nonconjugated Diolefin and Related Complexes 391</b></p> <p>22.1 Butadiene and Butatriene Complexes 391</p> <p>22.2 Pentadiene Complexes 396</p> <p>22.3 Hexadiene Complexes 398</p> <p>22.4 Miscellaneous Olefin Complexes 399</p> <p><b>Part II References 403</b></p> <p><b>Part III Cyclic, Unsaturated Organometallic Compounds 427</b></p> <p><b>23 Metal Complexes of Fullerenes and Other Nonlinear Carbon Clusters 429</b></p> <p><b>24 Three‐carbon Rings 433</b></p> <p><b>25 Four‐carbon Rings 435</b></p> <p><b>26 Five‐carbon Rings 441</b></p> <p>26.1 Cyclopentene and Cyclopentyl Complexes 441</p> <p>26.2 1,3‐Cyclopentadiene, Cyclopentadienone, and Related Complexes 441</p> <p>26.3 Anionic Cyclopentadienide Complexes 443</p> <p>26.4 Covalent Cyclopentadienyl Complexes 446</p> <p><b>27 Six‐carbon Rings 547</b></p> <p>27.1 Cyclohexene Complexes 547</p> <p>27.2 Cyclohexadiene, Cyclohexadienyl, Oxocyclohexadienyl, and Quinone Complexes 547</p> <p>27.3 Neutral, Cationic, and Anionic Phenyl Complexes 550</p> <p>27.4 Phenyl Compounds with Other Functional Groups 559</p> <p>27.5 Phenyl Complexes with Metal–Metal Bonds 585</p> <p>27.6 Ring‐Substituted Phenyl Complexes 588</p> <p>27.7 Perhalogenated Phenyl Complexes 591</p> <p>27.8 Benzene Ring Complexes 596</p> <p>27.9 Ring‐Substituted Benzene Complexes 608</p> <p>27.10 Benzyne Complexes 611</p> <p><b>28 Seven‐carbon Rings 613</b></p> <p><b>29 Eight‐carbon Rings 615</b></p> <p><b>30 Nine‐carbon Rings 629</b></p> <p><b>31 Ten‐carbon Rings 631</b></p> <p><b>32 Coupled Organic Ring Complexes 633</b></p> <p><b>33 Fused Organic Ring Complexes 635</b></p> <p>33.1 Pentalenyl Complexes 635</p> <p>33.2 Indene and Indenyl Complexes 635</p> <p>33.3 Fluorene and Fluorenyl Complexes 641</p> <p>33.4 Indacenyl Complexes 641</p> <p>33.5 Azulene Complexes 641</p> <p>33.6 Naphthalene and Larger Fused Aromatic Ring Complexes 642</p> <p>34 Miscellaneous Cyclic Olefin and Mixed Ring Complexes 643</p> <p>35 Carboranes and Metallacarboranes 647</p> <p>36 Five‐ and Six‐membered Heterocyclic Rings and Their Metal Complexes 651</p> <p>37 Unsaturated Metallacycle Rings with Four or More Atoms 657</p> <p><b>Part III References 661</b></p> <p>Index 709</p>

<p><b>Edward Maslowsky, Jr., Ph.D.,</b> is Professor Emeritus of Chemistry in the Division of Molecular, Life, and Health Science at Loras College, Dubuque, Iowa, USA.

<p><b>A comprehensive compilation of the available experimental and theoretical vibrational data for organometallic compounds and its role in evaluating the structures, bonding, and properties of these key compounds</b></p> <p>This unique book offers a thorough review of the literature dealing with vibrational data obtained using various phases, including matrices, reported for organometallic compounds from infrared spectra, Raman spectra, and several other techniques. It is the only work that compiles the available experimental and theoretical vibrational data on these compounds, and which discusses the importance of this information and its role in evaluating structures, bonding, and other important properties. It also treats the use of DFT and other theoretical calculations to analyze the vibrational data and to predict properties associated with these compounds. The book also includes vibrational data for organic species that form on metal and other surfaces.</p> <p><i>Vibrational Spectra of Organometallics: Theoretical and Experimental Data</i> offers complete coverage of: Carbide, Alkylidyne, Alkylidene, Alkyl, and Alkane Derivatives; Noncyclic Carbon Clusters and Unsaturated Hydrocarbon Derivatives; and Cyclic, Unsaturated Organometallic Derivatives. By summarizing work that has already been done on organometallic compounds, it serves as an important reference for those studying vibrational spectra leading to a clearer understanding of other research that needs to be done in order to help scientists determine new research directions.</p> <ul> <li>An important reference for those studying the vibrational spectra of organometallic compounds</li> <li>Gathers the existing experimental and theoretical vibrational data and discusses its significance in assessing structures, bonding, and other principal properties</li> <li>Includes DFT methods for the interpretation of spectra, which has been one of the major developments of the last two decades</li> </ul> <p><i>Vibrational Spectra of Organometallics: Theoretical and Experimental Data</i> is an important reference for researchers and practitioners in the areas of inorganic, organometallic, organic, and surface chemistry who have an interest in using vibrational data to characterize the bonding, composition, reactions, and structures of organometallic compounds, and organic species that are formed on various surfaces.</p>

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