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Preface. <p>Notice to Contributors.</p> <p><b>Chapter One Metal Complexes of Olefins.</b></p> <p>1 Bis(1.3.5 7-cyclooctatetraene)iron(0).</p> <p>2 Bis(1,4-cyclooctadiene)nickel(0).</p> <p>3 Ethylenebis(tri-<i>o</i>-tolyl phosphite)nickel(0) and Tris(tri-<i>o</i>-tolyl phosphite)nickel(0).</p> <p>4 Di-<i>µ</i>-chlorotetrakis(ethylene)dirhodium(I), 2,4-Pentanedionatobis(ethylene)rhodium(I), and Di-<i>µ</i>-chlorotetracarbonyldirhodium(I).</p> <p>5 Cyclooctene and 1,5-Cyclooctadiene Complexes of Iridium(I).</p> <p><b>Chapter Two Metal Complexes of Dinitrogen and of Hydrogen.</b></p> <p>6 <i>trans</i>(Dinitrogen)bis[ethylenebis(diethylphosphine)]hydridoiron(II).</p> <p>7 <i>trans</i>-Bis(dinitrogen)bis[ethylenebis(diphenylphosphine)]molybdenum(0).</p> <p>8 (<i>µ</i>-Dinitrogen-N,N')bis[bis(tricyclohexylphosphine)nickel(0)].</p> <p>9 Dinitrogen and Hydrogen Complexes of Ruthenium.</p> <p>10 Pentahydridobis(trimethylphosphine)iridium(V).</p> <p>11 Hydride Complexes of Iron(II) and Ruthenium(II).</p> <p>12 Tetrahydridotetrakis(methyldiphenylphosphine)molybdenum(IV).</p> <p><b>Chapter Three Triphenylphosphine Complexes of Transition Metals.</b></p> <p>13 Complexes of Ruthenium, Osmium, Rhodium, and Iridium Containing Hydride, Carbonyl, or Nitrosyl Ligands.</p> <p>14 Fluoro Complexes of Rhodium(I) and Iridium(I).</p> <p>15 Covalent Perchlorato Complexes of Iridium and Rhodium.</p> <p>16 <i>trans</i>-Carbonyl(cyanotrihydridoborato)bis(triphenylphosphine)rhodium(I).</p> <p><b>Chapter Four Other Transition-Metal Compounds.</b></p> <p>17 <i>p</i>-Allyl Complexes of Palladium and Platinum.</p> <p>18 Dicarbonylchloro(p-toluidine)iridium(I).</p> <p>19 <i>µ</i>-Nitrido-bis(triphenylphosphorus)(1+)(“PPN”) Salts with Metal.</p> <p>20 Dicarbonyl-<i>h</i>^{<small>5</small>}-cyclopentadienylnitrosylmanganese(1+) Hexafluorophosphate (1–).</p> <p>21 Hexammineplatinum(IV) Chloride.</p> <p>22 Bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)nickel(II)and-cobalt(II).</p> <p>23 Ammonium Pentahalooxomolybdates(2–).</p> <p>24 13-Vanadomanganate(IV) and Nickelate(IV).</p> <p><b>Chapter Five Boron Compounds.</b></p> <p>25 Octahydrotriborate(1–)([B_{<small>3</small>}H_{<small>8</small>}]^{<small>–</small>}) Salts.</p> <p>26 Pentaborane(9)([ B_{<small>5</small>}H_{<small>9</small>}]).</p> <p>27 Dimethylamine-Borane.</p> <p>28 Dimethylamine-Tribromoborane.</p> <p>29 Methyldiphenylphosphine-Borane and Dimethylphenylphosphine-Borane.</p> <p>30 Triphenylborane.</p> <p>31 Sodium Triethylhydroborate, Sodium Tetraethylborate, and Sodium Triethyl-1-propynylborate.</p> <p>32 Tetraalkyldiboranes and 9-Borabicyclo[3.3.1]nonane Dimer.</p> <p>33 Chlorodiethylborane and Chlorodiphenylborane.</p> <p><b>Chapter Six Germanium Hydride Derivatives.</b></p> <p>34 Bromogermane and Dibromogermane.</p> <p>35 Chlorogermane and Iodogermane.</p> <p>36 Fluorogermane and Digermylcarbodiimide.</p> <p>37 Iododigermane and Methyldigermane.</p> <p>38 Pentacarbonylgermylmanganese.</p> <p>39 Germylphosphine.</p> <p>40 Digermyl Sulfide(Digermthiane).</p> <p><b>Chapter Seven Phosphorous Compounds.</b></p> <p>41 Ethylenebis(dimethylphosphine)[1,2-bis(Dimethylphosphino)ethane], Tetramethyldiphosphane Disulfide, and Tetramethyldisphosphane.</p> <p>42 Dimethylphosphinothioic Chloride and Dimethylphosphinous Chloride.</p> <p>43 Phosphoric Trihalides.</p> <p>44 <i>µ</i>-Nitrido-bis[amidodiphenylphosphorus](1+) Chloride.</p> <p><b>Chapter Eight Main Group and Actinide Compounds.</b></p> <p>45 Trimethylgallium.</p> <p>46 Hexamethyldisilthiane and Hexamethylcyclotrisilthiane.</p> <p>47 Polyatomic Cations of Sulfur, Selenium, and Tellurium.</p> <p>48 Tetraethylammonium Trichlorogermanate(1–) and Tetrachlorostannate(1–).</p> <p>49 Weak and Unstable Anionic Bromo and Iodo Complexes.</p> <p>50 Hexahalouranate Salts.</p> <p>51 Pentachloro(trichloroacrylyl chloride)uranium(V).</p> <p>Index of Contributors.</p> <p>Subject Index.</p> <p>Formula Index.</p>

<strong>George W. Parshall</strong> is an organometallic chemist who made notable contributions to homogeneous catalysis. He was a senior scientist at E. I. du Pont de Nemours and Company for many years.

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