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Inorganic Reactions and Methods, The Formation of Bonds to N,P,As,Sb,Bi (Part 1)

Inorganic Reactions and Methods, Band 14 Volume 7

von: J. J. Zuckerman, A. P. Hagen
558,99 €
Verlag:	Wiley-VCH
Format:	PDF
Veröffentl.:	17.09.2009
ISBN/EAN:	9780470145425
Sprache:	englisch
Anzahl Seiten:	412

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Beschreibungen

Titelbeschreibung

This 18-volume series is a true first. In a clear, concise, and highly organized manner, it provides an in-depth treatment of bond formation reactions categorized by element type. The series presents current knowledge in all areas of inorganic chemistry including chemistry of the elements, coordination compounds, donor-acceptor adducts, organometallic, polymer and solid-state material, and compounds relevant to bioinorganic chemistry. A unique index system provides users with several fast options for accessing information on forming any bond type, compound, or reaction. Coverage of both classical chemistry and the frontiers of today's research makes this series a valuable reference for years to come.

Inhaltsverzeichnis

How to Use this Book Preface to the Series Editorial Consultants to the Series Contributors to Volume 7 4. The Formation of Bonds to the Elements of Group VB (N, P, As, Sb, Bi) 1 4.1. Introduction 2 4.2. Homoatomic Bonds 3 4.2.1. Introduction 3 4.2.2. Catenated Group VB Atoms 3 4.2.2.1. Involving Nitrogen-Nitrogen Bonds 3 4.2.2.1.1. from Oxidation-Reduction between Two Nitrogen-Containing Species 3 4.2.2.1.2. from the Oxidation of Nitrogen Compounds by Non-Nitrogen Oxidants 13 4.2.2.1.3. from the Reduction of Nitrogen Compounds by Non-Nitrogen Reductants 14 4.2.2.1.4. from Disproportionation 15 4.2.2.2. Involving Phosphorus-Phosphorus Bonds 17 4.2.2.2.1. in Elemental Phosphorus 17 4.2.2.2.2. in Phosphorus Allotropes 18 4.2.2.2.3. in Linear and Cyclic Di- and Polyphosphines 18 4.2.2.2.4. in Other Phosphorus-Phosphorus- Bonded Compounds 26 4.2.2.3. Involving Arsenic-Arsenic Bonds 29 4.2.2.3.1. by Conversion of Arsenic Compounds to the Free Element 30 4.2.2.3.2 in Arsenic, Antimony or Bismuth Allotropes 30 4.2.2.3.3 in Linear and Cyclic Di- and Polyarsines 31 Homoatomic Bonds 4.2.2.3.4. in Diarsenic Tetraiodide 37 4.2.2.4. Involving Antimony-Antimony or Bismuth-Bismuth Bonds 37 4.3. Heteroatomic Bonds 39 4.3.1 Introduction 39 4.3.2. Involving Nitrogen or Phosphorus 39 4.3.2.1 in Noncyclic Species 39 4.3.2.2. in Cyclic or Cage Compounds 49 4.3.3. Involving Nitrogen or Arsenic 54 4.3.3.1. in Noncyclic Species 54 4.3.3.2. in Cyclic or Cage Compounds 60 4.3.4. Involving Nitrogen and Antimony or Nitrogen and Bismuth 64 4.3.5. Involving Phosphorus or Arsenic 68 4.3.6. Involving Phosphorus and Antimony, Phosphorus and Bismuth, Arsenic and Antimony, Arsenic and Bismuth or Antimony and Bismuth 69 4.4. Formation of Bonds between Elements of Group VB (N, P, As, Sb, Bi) and Group IVB (C, Si, Ge, Sn, Pb) 71 4.4.1. Introduction 71 4.4.2. from the Elements 71 4.4.2.1. Giving Cyanogen and Group IVB Nitrides 71 4.4.2.2. Giving Group IVB Phosphides 71 4.4.2.3. Giving Group IVB Arsenides 72 4.4.2.4. Giving Alloys of Sb, Bi, and Group IVB Elements 72 4.4.3. in Reactions of Elemental N, P, As, Sb, Bi 73 4.4.3.1. with Carbon Compounds 73 4.4.3.1.1. and Nitrogen or Phosphorus 73 4.4.3.1.2. and As, Sb or Bi 74 4.4.3.2. with Si Compounds 75 4.4.3.3. with Ge Compounds 75 4.4.3.4. with Sn Compounds 75 4.4.3.5. with Pb Compounds 75 4.4.4. in Reactions of N, P, As, Sb, Bi Hydrides 75 4.4.4.1. with Carbon Halides 75 4.4.4.2. with Si Halides 76 4.4.4.2.1. by Ammonolysis or Aminolysis 76 4.4.4.2.2. by Reactions with Hydrides of P, As, Sb and Bi 4.4.4.3. with Ge Halides 78 4.4.4.3.1. by Ammonolysis or Aminolysis 78 4.4.4.3.2. by Reactions with Phosphines and Stibines 79 4.4.4.4. with Sn Halides 79 4.4.4.4.1. by Adduct Formation of Ammonia or Primary or Secondary Amines with Sn(ll) or Sn(IV) Halides 79 4.4.4.4.2. by Ammonolysis 81 4.4.4.4.3. Giving Sn-P or Sn-As Bonds 81 4.4.4.5. with Pb Halides 82 4.4.5. in Reactions of N, P, As, Sb, Bi Metal Derivatives 83 4.4.5.1. with Carbon Compounds 83 4.4.5.1.1. Giving Amines from Alkali Amides 83 4.4.5.1.2. Giving P-C Bonds 83 4.4.5.1.3. Giving As-C Bonds 84 4.4.5.1.4. Giving Sb-or Bi-C Bonds 84 4.4.5.2. with Si Compounds 85 4.4.5.2.1. Giving Si-N Bonds by Salt Elimination 85 4.4.5.2.2. Giving Si-P Bonds by Elimination of Alkali Chlorides 86 4.4.5.2.3. Giving Si-P Bonds from Al Phosphides 88 4.4.5.2.4. Giving Si-P Bonds by Cocondensation of Phosphorus and Si Halides with Mg or Hg 88 4.4.5.2.5. Giving Bonds of Si with As, Sb or Bi by Salt Elimination 89 4.4.5.3. with Ge Compounds 90 4.4.5.3.1. Giving Ge-N Bonds by Salt Elimination 90 4.4.5.3.2. Giving Ge-P Bonds 92 4.4.5.3.3. Giving Bonds of Ge with As, Sb or Bi 93 4.4.5.4. with Sn Compounds 94 4.4.5.4.1. Giving Sn-N Bonds 94 4.4.5.4.2. Giving Sn-P Bonds 96 4.4.5.4.3. Giving Bonds of Sn with As, Sb or Bi 97 4.4.5.5. with Pb Compounds 98 4.4.5.5.1. by Salt Elimination 98 4.4.5.5.2. by Exchange 99 4.4.6. in Reactions of N, P, As, Sb, Bi Halides 99 4.4.6.1. with Carbon Compounds 99 4.4.6.2. with Si Compounds 99 4.4.6.3. with Ge Compounds 100 4.4.6.4. with Sn Compounds 100 4.4.6.5. with Pb Compounds 101 4.4.7. in Reactions of Unsaturated Derivatives of N, P, As, Sb, Bi 101 4.4.7.1. with Carbon Compounds 101 Formation of Bonds between Elements of Group VB (N, P, As, Sb, Bi) and Group IVB (C, Si, Ge, Sn, Pb) 4.4.7.2. with Si Compounds 101 4.4.7.3. with Ge Compounds 102 4.4.7.4. with Sn Compounds 103 4.4.7.5 with Pb Compounds 104 4.4.8. in Reactions of Tertiary Amines 104 4.4.8.1. with Carbon Compounds 104 4.4.8.2. with Si Compounds 104 4.4.8.3. with Ge Compounds 105 4.4.8.4. with Sn Compounds 105 4.4.8.5. with Pb Compounds 106 4.4.9. in Reactions of Tertiary Phosphines, Arsines, Stibines and Bismuthines 107 4.4.9.1. with Carbon Compounds 107 4.4.9.2. with Si Compounds 107 4.4.9.3. with Ge Compounds 107 4.4.9.4. with Sn Compounds 108 4.4.9.5. with Pb Compounds 109 4.5. Formation of Bonds between Elements of Group VB (N, P, As, Sb, Bi) and Group IIIB (B, Al, Ga, In, Tl) 110 4.5.1. Introduction 110 4.5.2. from the Elements 110 4.5.3. in Reactions of Elemental N, P, As, Sb, Bi 112 4.5.3.1. with Boron Compounds 112 4.5.3.2. with Al Compounds 113 4.5.3.3. with Ga Compounds 113 4.5.3.4. with In and Tl Compounds 115 4.5.4. in Reactions of Compounds Containing N/P/As/Sb/Bi-N/P/As/Sb/Bi Bonds 116 4.5.4.1. with Boron Compounds 116 4.5.4.1.1. Giving Monohydrazinoboranes 116 4.5.4.1.2. Giving Bis(hydrazino)boranes 119 4.5.4.1.3. Giving Tris(hydrazino)boranes 120 4.5.4.1.4. Giving Azidoboranes 120 4.5.4.1.5. Giving Heterocycles Containing B-N or N-N Bonds 122 4.5.4.2. with Al Compounds 122 4.5.4.3. with Ga, In or Tl Compounds 123 4.5.5. in Reactions of N, P, As, Sb, Bi Hydrides with Hydrides or Complex Hydrides 123 4.5.5.1. of Boron 123 4.5.5.2. of Al 131 4.5.5.3. of Ga, In or Tl 132 4.5.6. in Reactions of N, P, As, Sb, Bi Hydrides with Halides 133 4.5.6.1. of Boron 133 4.5.6.1.1. Giving Boron Nitride from Ammonia 133 4.5.6.1.2. Giving Adducts 134 4.5.6.1.3. Giving Tris(amino)boranes or Tris(phosphino)boranes 135 4.5.6.1.4. Giving Bis(amino)boranes or Bis(phosphino)boranes 136 4.5.6.1.5. Giving Monoaminoboranes or Monophosphinoboranes 138 4.5.6.1.6. Giving Borazines, (RB-R'N)3 or Tetrameric Borazynes, (RB-R'N)4 141 4.5.6.1.7. Giving Imidoboranes 144 4.5.6.2. of Al 144 4.5.6.3. of Ga, In or Tl 145 4.5.7. in Reactions of N, P, As, Sb, Bi Hydrides with Group VIB Compounds 146 4.5.7.1. of Boron 146 4.5.7.1.1. and Oxygen 146 4.5.7.1.2. and Sulfur 150 4.5.7.2. of Al, Ga, In, Tl and Oxygen 153 4.5.8. in Reactions of N, P, As, Sb, Bi Hydrides with Group IIIB-Group VB Compounds 155 4.5.8.1. of Boron 155 4.5.8.1.1. and Nitrogen 155 4.5.8.1.2. and Phosphorus or Arsenic 160 4.5.8.2. of Al, Ga, In, Tl 160 4.5.8.2.1. and Nitrogen 160 4.5.8.3. and Al, Ga, In, Tl 162 4.5.9. in Reactions of N, P, As, Sb, Bi Hydrides with Group IIIB-Group IVB Compounds 162 4.5.9.1. Organoboranes 162 4.5.9.2. Organoalanes 164 4.5.9.2.1. and Nitrogen Hydrides 165 4.5.9.2.2. and P, As, Sb, Bi Hydrides 170 4.5.9.3. with Organic Derivatives of Ga, In, Tl 170 4.5.10. in Reactions of N, P, As, Sb, Bi Hydrides with Group IIIB-Group IIIB Compounds 174 4.5.10.1 Tetrahalodiborane(4) and Amines or Phosphines 174 4.5.10.2. by Transamination of Tetrakis(amino)diboranes(4) 174 4.5.11. in Reactions of N, P, As, Sb, Bi Hydride Anions 176 4.5.11.1. with Boron Halides 176 Formation of Bonds between Elements of Group VB (N, P, As, Sb, Bi) and Group IIIB (B, Al, Ga, In, TI) 4.5.11.1.1. Giving Tris(amin0)boranes and Related Compounds 176 4.5.11.1.2. Giving Bis(amino)boranes or Bis(phosphino)boranes 178 4.5.11.1.3. Giving Monoaminoboranes or Monophosphinoboranes 180 4.5.11.1.4. Giving Iminoboranes 181 4.5.11.1.5. Giving Diboryl Derivatives 182 4.5.11.1.6. Giving Heterocyclic B-N or B-P Compounds 182 4.5.11.2. with Aluminum Halides 183 4.5.11.3. with Halides of Ga, In, Tl 183 4.5.11.4. with Organic Derivatives of B, Al, Ga, In, Tl 183 4.5.12. in Reactions of N, P, As, Sb, Bi Halides 184 4.5.12.1. with Boron Compounds 184 4.5.12.2. with Aluminum Compounds 185 4.5.12.3. with Compounds of Ga, In, Tl 185 4.5.13. in Reactions of N, P, As, Sb, Bi Oxides, Alkoxides or Sulfur Compounds 186 4.5.14 in Reactions of N, P, As, Sb, Bi Derivatives 187 4.5.14.1 with Boron Hydrides 187 4.5.14.1.1. and Compounds with N-B Bonds 187 4.5.14.1.2. and Compounds with P-B Bonds 194 4.5.14.1.3. and Compounds with As-B or Sb-B Bonds 198 4.5.14.2. with Boron Halides 198 4.5.14.2.1. Giving Tris(amino)boranes or Bis(amino)phosphinoboranes 198 4.5.14.2.2. Giving Bis(amino)bornes 200 4.5.14.2.3. Giving Monoaminoboranes or Monophosphinoboranes 200 4.5.14.2.4 Giving Diborylamines or Triborylamines 202 4.5.14.2.5. Giving Borazines 203 4.5.14.2.6. Giving Other Heterocycles 204 4.5.14.3. with Other Boron Compounds 205 4.5.14.3.1. in Insertion Reactions 205 4.5.14.3.2. in Amination and Related Reactions 206 4.5.14.4. with Aluminum Compounds 206

Autorenportrait

J. J. Zuckerman is the editor of Inorganic Reactions and Methods, Volume 7, The Formation of Bonds to N,P,As,Sb,Bi, Part 1, published by Wiley. A. P. Hagen is the author of Inorganic Reactions and Methods, Volume 7, The Formation of Bonds to N,P,As,Sb,Bi, Part 1, published by Wiley.