Details

Controlled and Living Polymerizations


Controlled and Living Polymerizations

From Mechanisms to Applications
1. Aufl.

von: Krzysztof Matyjaszewski, Axel H. E. Müller

165,99 €

Verlag: Wiley-VCH
Format: PDF
Veröffentl.: 23.12.2009
ISBN/EAN: 9783527629107
Sprache: englisch
Anzahl Seiten: 634

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Beschreibungen

Written by a highly prestigious and knowledgeable team of top scientists in the field, this book provides an overview of the current status of controlled/living polymerization, combining the synthetic, mechanistic and application-oriented aspects.<br> From the contents:<br> * Anionic Vinyl Polymerization<br> * Carbocationic Polymerization<br> * Radical Polymerization<br> * Coordinative Polymerization of Olefins<br> * Ring-Opening Polymerization of Heterocycles<br> * Ring-Opening Metathesis Polymerization <br> * Macromolecular Architectures<br> * Complex Functional Macromolecules<br> * Synthesis of Block and Graft Copolymers<br> * Bulk and Solution Structures of Block Copolymers<br> * Industrial Applications <br> While some of the material is based on chapters taken from the four-volume work "Macromolecular Engineering", it is completely updated and rewritten to reflect the focus of this monograph.<br> Must-have knowledge for polymer and organic chemists, plastics technologists, materials scientists and chemical engineers.<br>
ANIONIC VINYL POLYMERIZATION<br> Introduction<br> Structure of Carbanions<br> Initiation<br> Mechanism of Styrene and Diene Polymerization<br> Mechanism of Anionic Polymerization of Acrylic Monomers<br> Some Applications of Anionic Polymerization<br> Conclusions and Outlook<br> CARBOCATIONIC POLYMERIZATION<br> Introduction<br> Mechanistic and Kinetic Details of Living Cationic Polymerization<br> Living Cationic Polymerization<br> Functional Polymers by Living Cationic Polymerization<br> Telechelic Polymers<br> Macromonomers<br> Linear Diblock Copolymers<br> Linear Triblock Copolymers<br> Block Copolymers with Nonlinear Architecture<br> Branched and Hyperbranched Polymers<br> Surface Initiated Polymerization -<br> Polymer Brushes<br> Conclusions<br> RADICAL POLYMERIZATION<br> Introduction<br> Typical Features of Radical Polymerization<br> Controlled Reversible-Deactivation Radical Polymerization<br> SFRP: NMP and OMRP Systems -<br> Examples and Peculiarities<br> ATRP -<br> Examples and Peculiarities<br> Degenerative Transfer Processes and RAFT<br> Relative Advantages and Limitations of SFRP, ATRP, and DT Processes<br> Controlled Polymer Architectures by CRP: Topology<br> Chain Composition<br> Functional Polymers<br> Applications of Materials Prepared by CRP<br> Outlook<br> LIVING TRANSITION METAL-CATALYZED ALKENE PUOLYMERIZATION: POLYOLEFIN SYNTHESIS AND NEW POLYMER ARCHITECTURES<br> Introduction<br> Living Alpha-Olefin Polymerization<br> Living Propylene Polymerization<br> Living Polymerization of Ethylene<br> Living Nonconjugated Diene Polymerization<br> Living Homo- and Copolymerization of Cyclic Olefins<br> Random Copolymers<br> Block Copolymers<br> Outlook and Summary<br> LIVING RING-OPENING POLYMERIZATION OF HETEROCYCLIC MONOMERS<br> Introduction<br> Anionic and Coordination Living Ring-Opening Polymerization (LROP)<br> Cationic CROP and LROP<br> CROP and LROP Conducted in Dispersions<br> Conclusions<br> LIVING RING-OPENING METATHESIS POLYMERIZATION<br> Overview of Ring-Opening Metathesis Polymerization (ROMP)<br> Initiators for Living ROMP<br> Applications of Polymers Synthesized using ROMP: From Novel Materials to Commerical Products<br> Challenges and Perspectives for the Future<br> Conclusion<br> MACROMOLECULAR ARCHITECTURES BY LIVING AND CONTROLLED/<br> LIVING POLYMERIZATIONS<br> Introduction<br> Star Polymers<br> Comb Polymers<br> Cyclic Polymers<br> Dendritic Polymers<br> Complex Macromolecular Architectures<br> Applications<br> Conclusions<br> SYNTHESIS OF BLOCK AND GRAFT COPOLYMERS<br> Introduction<br> Principles of Block Copolymerization<br> ABA Triblock Copolymers<br> (AB)n Linear Multiblock Copolymers<br> ABC Triblock Terpolymers<br> Synthesis of ABCA Tetra- and ABCBA Pentablock Terpolymers<br> Synthesis of ABCD Quaterpolymers<br> Applications<br> Concluding Remarks<br> MORPHOLOGIES IN BLOCK COPOLYMERS<br> Introduction<br> Block Copolymers in Bulk State<br> Block Copolymer Thin Films<br> Block Copolymer Micelles<br> Applications<br> Summary and Outlook<br> INDUSTRIAL APPLICATIONS<br> Introduction<br> Synthesis of Anionic Styrenic Block Copolymers<br> Adhesives and Sealants<br> Compounding Applications<br> Polymer Modification<br> Cross-Linked Systems<br> Bitumen Modification<br> Footwear<br> Viscosity Modification and Other Highly Diluted SBC Applications<br> Emerging Technology in Block Copolymers<br>
<p>"Written by a highly prestigious and knowledgeable team of top scientists in the field, this book provides an overview of the current status of controlled/living polymerisation, combining the synthetic, mechanistic and application-oriented aspects." (ET Polymers, 1 March 2011)</p> <p>"In summary, this book is an excellent resource for chemical professionals interested in controlled/living polymerization, and the clear, concise presentation of the mechanisms for such polymerizations accompanied by the comprehensive literature references renders this book useful to both novices and experts." (<i>JACS,</i> 2010)</p> All in all, Mu¨ller and Matyjaszewski have done a marvelous job. Their book deserves the label ‘‘must-have’’ for graduate students and academic or industrial scientists, who are either working or interested in the area of modern polymer synthesis (<span style="font-size: small;"><span style="font-family: Calibri;"><span style="font-size: small;"><span style="font-family: Calibri;"><span style="font-size: small;"><span style="font-family: Calibri;"><em style="mso-bidi-font-style: normal;"><span style="mso-fareast-font-family: 'Times New Roman'; mso-bidi-font-family: Tahoma;">Macromolecular Chemistry & Physics</span><span style="mso-fareast-font-family: 'Times New Roman'; mso-bidi-font-family: Tahoma;">, March 2010)</span></em></span></span></span></span></span></span>
Axel H.E. Muller holds the Chair of Macromolecular Chemistry at Bayreuth University, Germany. He received his academic degrees in chemistry from the University of Mainz, Germany, with G.V. Schulz. His research focuses on the synthesis and self-organization of well-defined polymer structures by living/controlled techniques. Professor Muller has contributed over 300 publications in polymer science. He received the IUPAC World Polymer Congress MACRO 2004 award "Distinguished Polymer Scientist". In addition, he has been coordinator of various European research networks, organizer of international meetings and is Senior Editor of the journal Polymer.<br> <br> Krzysztof Matyjaszewski is J.C. Warner Professor of Natural Sciences at Carnegie Mellon University in Pittsburgh, USA and also adjunct Professor at the Polish Academy of Sciences. His research focus is on macromolecular engineering, especially on the synthesis of well-defined copolymers using atom transfer radical polymerization and other controlled/living polymerization techniques. He is a member of the US National Academy of Engineering and the Polish Academy of Sciences and is the editor of the journals Progress in Polymer Science and Central European Journal of Chemistry. Professor Matyjaszewski authored 13 books, over 60 book chapters, more than 600 peer-reviewed publications and holds 38 US patents. He received several awards from the American Chemical Society, including the 2009 Presidential Award in Green Chemistry.
Written by a highly prestigious and knowledgeable team of top scientists in the field, this book provides an overview of the current status of controlled/living polymerization, combining the synthetic, mechanistic and application-oriented aspects.<br> <br> From the contents: <br> <br> * Anionic Vinyl Polymerization<br> * Carbocationic Polymerization<br> * Radical Polymerization<br> * Coordination Polymerization of Olefins<br> * Ring-Opening Polymerization of Heterocycles<br> * Ring-Opening Metathesis Polymerization<br> * Macromolecular Architectures<br> * Complex Functional Macromolecules<br> * Synthesis of Block and Graft Copolymers<br> * Bulk and Solution Structures of Block Copolymers<br> * Industrial Applications<br> <br> While some of the material is based on chapters taken from the four-volume work "Macromolecular Engineering", it is completely updated and rewritten to reflect the focus of this monograph.<br> <br> Must-have knowledge for polymer and organic chemists, plastics technologists, materials scientists and chemical engineers.

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