Table of Contents
Cover
Title Page
Copyright
Chapter 1: An Introduction to Chiral Nanomaterials: Origin, Construction, and Optical Application
1.1 Introduction
1.2 Chiral Noble Metal Clusters
1.3 Chiral Plasmonic Nanostructures
1.4 Optical Application of Chiral Noble Metal Nanostructures
1.5 Perspectives
References
Chapter 2: Chirality at Nanoscale – Theory and Mechanism
2.1 Introduction
2.2 Brief Introduction to the Theoretical Background
2.3 The Twist Rod Model
2.4 Induced Chirality in Hybrid Nanostructures Made of Chiral Molecules and QDs
2.5 Induced Chirality in Hybrid Nanostructures Made of Chiral Molecules and Metal Nanoparticles
2.6 Induced Chirality in Hybrid Nanostructures Made of Chiral Quantum Dots and Metal Nanoparticles
References
Chapter 3: Plasmonic Chiral Materials
3.1 Introduction
3.2 Fabrication of Plasmonic Chiral Nanomaterials
3.3 Properties of Plasmonic Chiral Nanomaterials
3.4 Applications of Plasmonic Chiral Nanomaterials
3.5 Conclusions
Acknowledgments
References
Chapter 4: Optically Active and Chiral Semiconductor Nanocrystals
4.1 Introduction
4.2 Chiroptically Active Excitonic Nanocrystals
4.3 Effects That Emerge from Chiral Arrangement of Nanocrystals
4.4 Nanocrystals with Chiral Crystal Symmetry (Chiral Atomic Arrangement)
4.5 Nanostructures with Chiral Shape
4.6 Summary and Outlook
References
Chapter 5: Chirality in Gold Nanoclusters
5.1 Introduction
5.2 The Origin of Chirality in Au
n
(SR)
m
Nanoclusters
5.3 X-ray Structures of Chiral Au
n
(SR)
m
Nanoclusters
5.4 Separation of Racemic Gold Nanoclusters and Their Chiroptical Properties
5.5 Other Chirality Origins in Gold Nanoclusters
5.6 Conclusion
Acknowledgment
References
Chapter 6: Chiral Mesoporous Silica Materials
6.1 Introduction
6.2 Chiral Mesoporous Materials Templated by Artificial Amphiphiles
6.3 Chiral Mesoporous Materials Template by DNA
6.4 Chiral Mesoporous Materials Templated by Peptides
6.5 Chiral Mesoporous Materials Templated by Polysaccharides
6.6 Summary and Outlook
References
Chapter 7: DNA-Based Chiral Nanostructures
7.1 Introduction
7.2 Preparation of DNA-Directed Chiral Nanostructures
7.3 Typical Chiral Nanocrystals and Nanoassemblies
7.4 Origin of Chiroplasmonic Activities
7.5 Conclusions
References
Chapter 8: Applications in Catalysis
8.1 Introduction
8.2 Asymmetric Hydrogenation Reactions Catalyzed by Chiral Metal Nanoparticles
8.3 Asymmetric C−C Bond-Forming Reactions Catalyzed by Chiral Metal Nanoparticles
8.4 Summary
References
Chapter 9: Applications in Polymer Science
9.1 Introduction
9.2 Preparation of Chiral Polybissilsesquioxanes
9.3 Characterization of Chiral Polybissilsesquioxanes
9.4 Applications of Chiral Polybissilsesquioxanes
9.5 Conclusion
References
Index
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