CONTENTS

Cover

Title Page

List of Contributors

Preface

Part One: Fundamentals

Chapter 1: Overview of Magnetic Nanomaterials
1. 1.1 Introduction
2. 1.2 Typical Characterization of Magnetic Nanomaterials
3. 1.3 Conclusions
4. References
Chapter 2: Magnetism of Nanomaterials
1. 2.1 Introduction
2. 2.2 Nanomagnetic Phenomena of Atomic Origin
3. 2.3 Micromagnetics
4. 2.4 Spin-Dependent Transport
5. Appendices
6. Appendix 2.A: Functional Derivatives and Materials Equations
7. Appendix 2.B: Relativistic Physics
8. Appendix 2.C: Unit Conversion in Magnetism
9. Acknowledgments
10. References

Part Two: Synthesis

Chapter 3: Overview of Synthesis of Magnetic Nanomaterials
1. 3.1 Introduction
2. 3.2 General Synthesis Mechanism of Magnetic Nanoparticles
3. 3.3 Typical Methods and Equipment of Magnetic Nanomaterials Synthetic Techniques: Chemical Approaches
4. 3.4 Typical Methods and Equipment of Magnetic Nanomaterials Synthetic Techniques: Physical Approaches
5. 3.5 Conclusions and Perspectives
6. References
Chapter 4: Synthesis of Soft Magnetic Nanomaterials and Alloys
1. 4.1 Introduction
2. 4.2 Nanoparticles
3. 4.3 Nanorods
4. 4.4 Thin Films
5. 4.5 Ribbons
6. 4.6 Conclusions
7. References
Chapter 5: Synthesis of Nanostructured Rare-Earth Permanent Magnets
1. 5.1 Introduction
2. 5.2 RCox-Based (R = Sm, Pr, Y, La) Nanostructured Magnets
3. 5.3 R2Fe14B-Based (R = Pr, Nd, Tb, Dy) Magnets
4. 5.4 Conclusions and Perspectives
5. References
Chapter 6: Synthesis of Rare Earth Free Permanent Magnets
1. 6.1 Introduction
2. 6.2 Tetragonal L10 FeCo
3. 6.3 MnBi Low-Temperature Phase
4. 6.4 Conclusions and Perspective
5. Acknowledgment
6. References
Chapter 7: Synthesis and Properties of Magnetic Chalcogenide Nanostructures
1. 7.1 Introduction
2. 7.2 Synthesis Methods of Binary Magnetic Chalcogenide Nanostructures
3. 7.3 Synthesis Methods of Ternary and Higher Order Magnetic Chalcogenides Nanostructures
4. 7.4 Structural and Magnetic Characterizations of Magnetic Chalcogenide Nanostructures
5. 7.5 Potential Applications of Magnetic Chalcogenide Nanostructures
6. 7.6 Conclusions and Perspectives
7. Acknowledgments
8. References
Chapter 8: Magnetic Multicomponent Heterostructured Nanocrystals
1. 8.1 Introduction
2. 8.2 Synthesis of Heterostructured Nanocrystals: Basic Concepts and Guiding Criteria
3. 8.3 Heterostructures with Core/Shell Geometries
4. 8.4 Nanohetero-Oligomer Architectures
5. 8.5 Conclusions
6. Acknowledgment
7. References
Chapter 9: Wet-Phase Synthesis of Typical Magnetic Nanoparticles with Controlled Morphologies
1. 9.1 Introduction
2. 9.2 Synthesis of Hollow/Porous Magnetic Nanoparticles
3. 9.3 Conclusions and Perspectives
4. Acknowledgment
5. References
Chapter 10: Self-Assembly of Co Nanocrystals Self-Assembled in 2D and 3D Superlattices: Chemical and Physical Specific Properties
1. 10.1 Introduction
2. 10.2 Control of Crystalline Structure of Nanoparticles (Nanocrystallinity) and the Nanocrystal Size
3. 10.3 Nano-Kirkendall Effect on Co Nanocrystals: Influence of Size and Nanocrystallinity [51–54]
4. 10.4 3D Self-Assemblies of Magnetic Supracrystals: Various Structures and Specific Behaviors
5. 10.5 3D Self-Assemblies of Magnetic Supracrystals: Physical Properties
6. 10.6 Conclusions
7. Acknowledgment
8. References

Part Three: Applications

Chapter 11: Magnetic Nanoparticles for Bioseparation, Biosensing, and Regenerative Medicine
1. 11.1 Introduction
2. 11.2 Synthesis and Modification of High-Moment Magnetic Nanoparticles
3. 11.3 Magnetic Nanomaterials for Bioseparation
4. 11.4 Magnetic Nanoparticles for Magnetic Biosensing
5. 11.5 Magnetic Nanoparticles for Regenerative Medicine
6. 11.6 Challenges and Perspectives
7. References
Chapter 12: Magnetic Nanomaterials for Diagnostics
1. 12.1 Introduction
2. 12.2 Biocompatibility of Magnetic Nanoparticles
3. 12.3 Surface Functionalization of Magnetic Nanomaterials
4. 12.4 Magnetic Resonance Imaging (MRI)
5. 12.5 Magnetoacoustic Tomography (MAT)
6. 12.6 Magnetic Particle Imaging (MPI)
7. 12.7 Multimodality Imaging
8. 12.8 Conclusions and Perspectives
9. References
Chapter 13: Magnetic Nanomaterials for Therapy
1. 13.1 Introduction
2. 13.2 Imaging-Guided Therapy Using Magnetic Nanomaterials
3. 13.3 Magnetic Hyperthermia
4. 13.4 Targeted Drug Delivery
5. 13.5 Targeted Gene Delivery
6. 13.6 Manipulation of Cellular Functions
7. 13.7 Conclusions and Perspectives
8. Acknowledgments
9. References
Chapter 14: Magnetic Nanomaterials for Data Storage
1. 14.1 Introduction: Magnetic Data Storage and its Requirements on Magnetic Nanomaterials
2. 14.2 Nanostructured Magnetic Thin Films for Data Storage: Overview of Perpendicular Recording (PMR) Media
3. 14.3 Nanostructured Magnetic Thin Films for Data Storage: Overview of FePt Media for Heat-Assisted Magnetic Recording (HAMR)
4. 14.4 Monodisperse Magnetic Nanoparticles: Synthesis, Phase Transition, Orientation Control, and Nanocomposites
5. 14.5 Patterned Magnetic Nanostructures for Bit Patterned Media Through Bottom-Up Approach: Self-Assembly and Guided Assembly of Block Copolymer
6. 14.6 Patterned Magnetic Nanostructures for Bit Patterned Media Through Top-Down Approach: Lithograph
7. 14.7 Conclusions and Perspectives
8. References
Chapter 15: Magnetic Nanomaterials for Electromagnetic Wave Absorption
1. 15.1 Introduction
2. 15.2 Magnetic Nanosized Powders and Composites
3. 15.3 Nanosized Carbon Materials with Magnetic Components
4. 15.4 Concluding Remarks
5. References
Chapter 16: Magnetic Nanomaterials for Water Remediation
1. 16.1 Introduction
2. 16.2 Magnetic Nanomaterials for Adsorption and Removal of Pollutants in Water
3. 16.3 Magnetic Nanomaterials for Catalytic Degradation of Wastewater
4. 16.4 Magnetic Nanomaterials for Wastewater Resources Recovery
5. 16.5 Magnetic Nanomaterials for Monitoring and Analysis Technologies
6. 16.6 Conclusion and Perspectives
7. Acknowledgment
8. References

Index

End User License Agreement

List of Illustrations

Figure 1.1

Figure 1.2

Figure 1.3

Figure 1.4

Figure 1.5

Figure 1.6

Figure 1.7

Figure 1.8

Figure 1.9

Figure 1.10

Figure 1.11

Figure 1.12

Figure 1.13

Figure 2.1

Figure 2.2

Figure 2.3

Figure 2.4

Figure 2.5

Figure 2.6

Figure 2.7

Figure 2.8

Figure 2.9

Figure 2.10

Figure 2.11

Figure 2.12

Figure 2.13

Figure 2.14

Figure 2.15

Figure 2.16

Figure 2.17

Figure 2.18

Figure 2.19

Figure 2.20

Figure 2.21

Figure 2.22

Figure 2.23

Figure 2.24

Figure 2.25

Figure 2.26

Scheme 3.1

Figure 3.1

Figure 3.2

Figure 3.3

Scheme 3.2

Figure 3.4

Figure 3.5

Figure 3.6

Figure 3.7

Figure 3.8

Figure 3.9

Figure 3.10

Figure 3.11

Figure 3.12

Figure 3.13

Figure 3.14

Figure 3.15

Figure 3.16

Figure 3.17

Figure 3.18

Figure 4.1

Figure 4.2

Figure 4.3

Figure 4.4

Figure 4.5

Figure 4.6

Figure 4.7

Figure 4.8

Figure 4.9

Figure 5.1

Figure 5.2

Figure 5.3

Figure 5.4

Figure 5.5

Figure 5.6

Figure 5.7

Figure 5.8

Figure 5.9

Figure 5.10

Figure 5.11

Figure 5.12

Figure 5.13

Figure 5.14

Figure 6.1

Figure 6.2

Figure 6.3

Figure 6.4

Figure 6.5

Figure 6.6

Figure 6.7

Figure 6.8

Figure 6.9

Figure 6.10

Figure 6.11

Figure 7.1

Figure 7.2

Figure 7.3

Figure 7.4

Figure 7.5

Figure 7.6

Figure 7.7

Figure 7.8

Scheme 8.1

Scheme 8.2

Figure 8.1

Figure 8.2

Figure 8.3

Scheme 8.3

Figure 8.4

Figure 8.5

Figure 8.6

Figure 8.7

Figure 8.8

Figure 8.9

Figure 8.10

Figure 8.11

Scheme 8.4

Figure 8.12

Figure 8.13

Figure 8.14

Figure 9.1

Figure 9.2

Figure 9.3

Figure 9.4

Figure 9.5

Figure 9.6

Figure 9.7

Figure 9.8

Figure 9.9

Figure 9.10

Figure 9.11

Figure 9.12

Figure 9.13

Figure 9.14

Figure 9.15

Figure 9.16

Figure 9.17

Figure 9.18

Figure 9.19

Figure 10.1

Figure 10.2

Figure 10.3

Figure 10.4

Figure 10.5

Figure 10.6

Figure 11.1

Figure 11.2

Figure 11.3

Figure 11.4

Figure 11.5

Figure 11.6

Figure 12.1

Figure 12.2

Figure 12.3

Figure 12.4

Figure 12.5

Figure 12.6

Figure 12.7

Figure 12.8

Figure 12.9

Figure 12.10

Figure 12.11

Figure 12.12

Figure 13.1

Figure 13.2

Figure 13.3

Figure 13.4

Figure 13.5

Figure 13.6

Figure 13.7

Figure 13.8

Figure 13.9

Figure 13.10

Figure 13.11

Figure 13.12

Figure 13.13

Figure 13.14

Figure 13.15

Figure 13.16

Figure 13.17

Figure 13.18

Figure 13.19

Figure 14.1

Figure 14.2

Figure 14.3

Figure 14.4

Figure 14.5

Figure 14.6

Figure 14.7

Figure 14.8

Figure 14.9

Figure 14.10

Figure 14.11

Figure 14.12

Figure 14.13

Figure 14.14

Figure 14.15

Figure 14.16

Figure 14.17

Figure 14.18

Figure 15.1

Figure 15.2

Figure 15.3

Figure 15.4

Figure 15.5

Figure 15.6

Figure 15.7

Figure 15.8

Figure 15.9

Figure 15.10

Figure 15.11

Figure 15.12

Figure 15.13

Figure 15.14

Figure 15.15

Figure 15.16

Figure 15.17

Figure 15.18

Figure 15.19

Figure 15.20

Figure 15.21

Figure 15.22

Figure 15.23

Figure 15.24

Figure 15.25

Figure 15.26

Figure 15.27

Figure 15.28

Figure 15.29

Figure 15.30

Figure 16.1

Figure 16.2

Figure 16.3

Figure 16.4

Figure 16.5

Figure 16.6

Figure 16.7

Figure 16.8

Figure 16.9

Figure 16.10

Figure 16.11

Figure 16.12

List of Contributors

Balamurugan Balasubramanian

University of Nebraska

Department of Physics and Astronomy and Nebraska Center for Materials and Nanoscience

855 N 16th Street

Lincoln, NE 68588

USA

Luigi Carbone

CNR NANOTEC

Institute of Nanotechnology

sede di Lecce, c/o Campus Ecotekne, via Monteroni

73100 Lecce

Italy

Xiaoyuan Chen

National Institute of Health

National Institute of Biomedical Imaging and Bioengineering

Laboratory of Molecular Imaging and Nanomedicine

35A Convent Dr

Bethesda, MD 20892

USA

Xin Chu

Peking University

College of Engineering

Department of Materials Science and Engineering

5 Yi He Yuan Road

Beijing 100871

China

Pantaleo Davide Cozzoli

CNR NANOTEC

Institute of Nanotechnology

sede di Lecce, c/o Campus Ecotekne, via Monteroni

73100 Lecce

Italy

and

University of Salento

Department of Mathematics and Physics “E. De Giorgi”

c/o Campus Ecotekne, via Monteroni

73100 Lecce

Italy

Angela Fiore

CNR NANOTEC

Institute of Nanotechnology

sede di Lecce, c/o Campus Ecotekne, via Monteroni

73100 Lecce

Italy

and

University of Salento

Department of Mathematics and Physics “E. De Giorgi”

c/o Campus Ecotekne, via Monteroni

73100 Lecce

Italy

Arunava Gupta

University of Alabama

Center for Materials for Information Technology

Tom Bevill Building, 201 7th Avenue

Tuscaloosa, AL 35487

USA

George C. Hadjipanayis

University of Delaware

Department of Physics and Astronomy

104 The Green

Newark, DE 19716

USA

Yiyuan Han

Nanyang Technological University

School of Chemical and Biomedical Engineering

70 Nanyang Drive

637457 Singapore

Singapore

Yu Hong

Beijing Forestry University

Beijing Key Lab for Source Control Technology of Water Pollution

No. 35 East Qinghua Road, Haidian District

100083 Beijing

China

Yanglong Hou

Peking University

College of Engineering

Department of Materials Science and Engineering

5 Yi He Yuan Road

Beijing 100871

China

Taeghwan Hyeon

Institute for Basic Science (IBS)

Center for Nanoparticle Research

1 Gwanak-ro, Gwanak-gu

151-742 Seoul

Korea

and

Seoul National University

School of Chemical and Biological Engineering

1 Gwanak-ro, Gwanak-gu

151-742 Seoul

Korea

Ling Bing Kong

Nanyang Technological University

School of Materials Science and Engineering

50 Nanyang Avenue

639798 Singapore

Singapore

Chih-Huang Lai

National Tsing Hua University

College of Engineering

Department of Materials Science and Engineering

101, Sec. 2, KungFu Rd.

300 Hsinchu

Taiwan

Song Lan

Case Western Reserve University

Department of Materials Science and Engineering

10900 Euclid Avenue

Cleveland, OH44106

USA

Sean Li

The University of New South Wales

School of Materials Science and Engineering

Sydney

NSW 2502

Australia

Jung-Wei Liao

University of Cambridge

Cavendish Laboratory

J. J. Thomson Avenue

CB3 0HE Cambridge

United Kingdom

and

National Tsing Hua University

College of Engineering

Department of Materials Science and Engineering

101, Sec. 2, KungFu Rd.

300 Hsinchu

Taiwan

Daishun Ling

Zhejiang University

College of Pharmaceutical Sciences

866 Yuhangtang Road

310058 Hangzhou

China

and

Zhejiang University

College of Biomedical Engineering & Instrument Science

38 Zhejiang University Road

310058 Hangzhou

China

Jia Liu

Beijing Institute of Technology

School of Materials Science & Engineering

Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications

5 South Zhongguancun Street, Haidian District

Beijing 100081

China

Jiajia Liu

Beijing Institute of Technology

School of Materials Science & Engineering

Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications

5 South Zhongguancun Street, Haidian District

Beijing 100081

China

Lie Liu

General Test Systems Inc.

Taohuayuan Science and Technology Innovation Park

Shenzhen

518102 Guangdong

China

Peirui Liu

Beijing Forestry University

Beijing Key Lab for Source Control Technology of Water Pollution

No. 35 East Qinghua Road, Haidian District

100083 Beijing

China

Concetta Nobile

CNR NANOTEC

Institute of Nanotechnology

sede di Lecce, c/o Campus Ecotekne, via Monteroni

73100 Lecce

Italy

Soubantika Palchoudhury

University of Tennessee at Chattanooga

Civil and Chemical Engineering

615 McCallie Ave

Chattanooga, TN 37403

USA

Marie-Paule Pileni

CEA Saclay

IRAMIS

Gif-sur-Yvette

91191 Paris

France

Shuang Qiao

Peking University

College of Engineering

Department of Materials Science and Engineering

5 Yi He Yuan Road

Beijing 100871

China

Karthik Ramasamy

Los Alamos National Laboratory

Center for Integrated Nanotechnologies

PO Box 5800, MS 1315

Albuquerque, NM 87185

USA

Shenqiang Ren

Temple University

Temple Material Institute and Mechanical Engineering

1947 North 12th Street

Philadelphia, PA 19122

USA

Riccardo Scarfiello

CNR NANOTEC

Institute of Nanotechnology

sede di Lecce, c/o Campus Ecotekne, via Monteroni

73100 Lecce

Italy

and

University of Salento

Department of Mathematics and Physics “E. De Giorgi”

c/o Campus Ecotekne, via Monteroni

73100 Lecce

Italy

David J. Sellmyer

University of Nebraska

Department of Physics and Astronomy and Nebraska Center for Materials and Nanoscience

855 N 16th Street

Lincoln, NE 68588

USA

Ralph Skomski

University of Nebraska

Department of Physics and Astronomy and Nebraska Center for Materials and Nanoscience

855 N 16th Street

Lincoln, NE 68588

USA

Shouheng Sun

Brown University

Department of Chemistry

324 Brook Street

Providence, RI 02912

USA

Min Wang

Nanyang Technological University

School of Chemical and Biomedical Engineering

70 Nanyang Drive

637457 Singapore

Singapore

Matthew A. Willard

Case Western Reserve University

Department of Materials Science and Engineering

10900 Euclid Avenue

Cleveland, OH44106

USA

Chenjie Xu

Nanyang Technological University

School of Chemical and Biomedical Engineering

70 Nanyang Drive

637457 Singapore

Singapore

and

Nanyang Technological University

NTU-Northwestern Institute of Nanomedicine

50 Nanyang Avenue

639798 Singapore

Singapore

Meng Xu

Beijing Institute of Technology

School of Materials Science & Engineering

Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications

5 South Zhongguancun Street, Haidian District

Beijing 100081

China

Jinbo Yang

Peking University

School of Physics

Collaborative Innovation Center of Quantum Matter

5 Yi He Yuan Road

Haidian District

Beijing 100871

China

Zhihong Yang

Nanjing University of Aeronautics and Astronautics

College of Materials Science and Technology

Changkong Road, Baixia District

211100 Nanjing

China

Ziyu Yang

Peking University

College of Engineering

Department of Materials Science and Engineering

5 Yi He Yuan Road

Beijing 100871

China

Ming Yue

Beijing University of Technology

College of Materials Science and Engineering

100 Pingleyuan

100124 Beijing

China

Hong-Wei Zhang

Nanyang Institute of Technology

School of Electronic and Electrical Engineering

Nanyang

473004 Henan

China

Jiatao Zhang

Beijing Institute of Technology

School of Materials Science & Engineering

Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications

5 South Zhongguancun Street, Haidian District

Beijing 100081

China

Tianshu Zhang

Anhui Target Advanced Ceramics Technology Co. Ltd.

Hightech Zone, Yulan Road No. 767

Hefei

Anhui

China

Zijian Zhou

National Institute of Health

National Institute of Biomedical Imaging and Bioengineering

Laboratory of Molecular Imaging and Nanomedicine

35A Convent Dr

Bethesda, MD 20892

USA

Magnetic Nanomaterials

Fundamentals, Synthesis and Applications

List of Contributors

Preface

Part One
Fundamentals