Table of Contents
Cover
Title Page
Copyright
List of Contributors
Preface
Chapter 1: Magnetism
1.1 Origin of Magnetism
1.2 Macroscopic Approach
1.3 Units in Magnetism
1.4 Ground State of an Ion and Hund's Rules
1.5 An Atom in a Magnetic Field
1.6 Mechanisms of Magnetic Interactions
1.7 Collective Magnetic State
1.8 Applications and Research
References
Chapter 2: Molecular Magnetism
2.1 Introduction
2.2 Birth of the Topic: Exchange-Coupled Clusters
2.3 Evolution of the Topic: Molecule-Based Magnets
2.4 Burgeoning Topics: Single-Molecule Magnets
2.5 Single-Chain Magnets
2.6 Spin Crossover Complexes
2.7 Charge Transfer-Induced Spin Transitions
2.8 Multifunctional Materials
2.9 Future Perspectives
References
Chapter 3: High-Spin Molecules
3.1 Introduction
3.2 Strategies for High-Spin Molecules
3.3 High-Spin Molecules based on d-Metal Ions
3.4 High-Spin Molecules Based on f-Metal Ions
3.5 High-Spin Molecules Based on d–f Metal Ions
3.6 Conclusions and Perspectives
References
Chapter 4: Single Molecule Magnets
4.1 Introduction
4.2 Measurement Techniques
4.3 Rational Design of SMMs
4.4 Family of SMMs
4.5 Conclusions and Perspectives
References
Chapter 5: Magnetic Molecules as Spin Qubits
5.1 Introduction
5.2 Molecular Qubits
5.3 Schemes for Two-Qubit Gates
5.4 Conclusions and Perspectives
Appendix: The Basics
List of Acronyms
References
Chapter 6: Single-Chain Magnets
6.1 Introduction
6.2 The Very Basics
6.3 Synthetic Endeavors Toward SCMs
6.4 Theoretical Modeling
6.5 New Directions
6.6 Conclusions and Perspectives
References
Chapter 7: High-Tc Ordered Molecular Magnets
7.1 Introduction
7.2 TCNE-Based Molecule-Based Magnets
7.3 Prussian Blue Analogs
7.4 Hepta- and Octacyanido-based Molecule-based Magnets
7.5 Conclusions and Perspectives
References
Chapter 8: Thin Layers of Molecular Magnets
8.1 Introductory Remarks
8.2 Thin Layers of Single-Molecule Magnets
8.3 Thin Layers of Antiferromagnetic Spin Clusters
8.4 Thin Layers of High-Spin Cages
8.5 Thin Layers of Molecular Magnets with Extended Networks
8.6 Conclusions and Perspectives
Acknowledgments
References
Chapter 9: Spin Crossover Phenomenon in Coordination Compounds
9.1 Introduction
9.2 Spin Crossover in the Solid and Liquid States
9.3 Multifunctionality in Spin Crossover Compounds
9.4 Spin Crossover Phenomenon in Soft Matter
9.5 Spin crossover Phenomenon at the Nanoscale
9.6 Charge Transport Properties of Single-Spin Crossover Molecules
9.7 Conclusion
References
Chapter 10: Porous Molecular Magnets
10.1 Introduction
10.2 PMMs with Spin-State Switching
10.3 PMMs with Slow Relaxation of Magnetization
10.4 PMMs with Long-Range Magnetic Ordering
10.5 PMMs with Switching Between Ferromagnetism and Antiferromagnetism
10.6 PMMs with the Magnetism-Modified Through Postsynthetic Process
10.7 Conclusions and Perspectives
References
Chapter 11: Molecular Magnetic Sponges
11.1 Introduction
11.2 The First Molecular Magnetic Sponge Systems
11.3 CN-Bridged Molecular Magnetic Sponges
11.4 Molecular Magnetic Sponges with Bridging Ligands Other Than Cyanide
11.5 Conclusions and Perspectives
References
Chapter 12: Non-Centrosymmetric Molecular Magnets
12.1 Introduction
12.2 Synthetic Strategies Toward Non-centrosymmetric Magnets (NCM)
12.3 Physicochemical Properties of Non-centrosymmetric Magnets
12.4 Conclusion
Acknowledgment
References
Chapter 13: Molecular Photomagnets
13.1 Introduction
13.2 Photomagnetic Coordination Networks based on [
M
(CN)
x
] (
x
= 6 or 8)
13.3 Photomagnetic Polynuclear Molecules Based on [
M
(CN)
x
] (
x
= 6 or 8)
13.4 Conclusions and Perspectives
References
Chapter 14: Luminescent Molecular Magnets
14.1 Introduction
14.2 Electronic Structure of Lanthanide Ions
14.3 Luminescence of Lanthanide Ions
14.4 Magnetism of Lanthanide Ions
14.5 Synthetic Strategies to Obtain Luminescent SMMs
14.6 Luminescent Lanthanide Single Molecule Magnets
14.7 NIR Luminescent-Prolate Lanthanides
14.8 Conclusions and Perspectives
References
Chapter 15: Conductive Molecular Magnets
15.1 Introduction
15.2 Design of Metal Complexes with TTF-Containing Ligands
15.3 Hybrid Arrangements of Magnetic Layers and Conducting Stacked Layers
15.4 Conductive Magnetic Coordination Frameworks
15.5 Purely Organic Systems
15.6 Conclusions and Perspectives
References
Chapter 16: Molecular Multiferroics
16.1 Multiferroicity
16.2 Classification of Multiferroic Materials
16.3 Classification of Molecular Multiferroics
16.4 Metal–Organic Framework Compounds and Hybrid Perovskites
16.5 Charge Order Multiferroics
16.6 Conclusions and Perspectives
References
Chapter 17: Modeling Magnetic Properties with Density Functional Theory-Based Methods
17.1 Introduction
17.2 Theoretical Analysis of Spin Crossover Systems
17.3 DFT Methods to Evaluate Exchange Coupling Constants
17.4 DFT Methods to Calculate Magnetic Anisotropy Parameters
17.5 DFT Approaches to Calculate Transport Through Magnetic Molecules
References
Chapter 18: Ab Initio Modeling and Calculations of Magnetic Properties
18.1 Introduction
18.2
Ab Initio
Calculations
18.3 Spin Hamiltonian Calculations
References
Index
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Guide
Cover
Table of Contents
Preface
Begin Reading