Table of Contents
Cover
Title Page
Copyright
Chapter 1: An Overview of the Physical and Photophysical Properties of [Ru(bpy)3]2+
1.1 Introduction
1.2 [Ru(bpy)
3
]
2+
: Optical and Electrochemical Properties
1.3 Excited State Kinetics
1.4 Excited-State Reactivity of [Ru(bpy)
3
]
2+
1.5 Energy Transfer: Förster and Dexter Mechanisms
1.6 Electron Transfer
1.7 Probing the Mechanism, Stage I: Stern–Volmer Quenching Studies
1.8 Probing the Mechanism, Stage II: Electron Versus Energy Transfer
1.9 Designing Photocatalysts: [Ru(bpy)
3
]
2+
as a Starting Point
1.10 Conclusion
References
Chapter 2: Visible-Light-Mediated Free Radical Synthesis
2.1 Introduction
2.2 Basics of the Photocatalytic Cycle
2.3 Generation of Radicals
2.4 C−X Bond Formation
2.5 C−C Bond Formation
2.6 Radical Cascade Applications
References
Chapter 3: Atom Transfer Radical Addition using Photoredox Catalysis
3.1 Introduction
3.2 Transition Metal-Catalyzed ATRA
3.3 Other Photocatalysts for ATRA Transformations
3.2 Semiconductor
3.4 Atom Transfer Radical Cyclization (ATRC)
3.5 Atom Transfer Radical Polymerization (ATRP)
3.6 Conclusion
References
Chapter 4: Visible Light Mediated α-Amino C−H Functionalization Reactions
4.1 Introduction
4.2 Visible Light Mediated α-Amino C−H Functionalization Via Iminium Ions
4.3 Visible Light Mediated α-Amino C−H Functionalization Via α-Amino Radicals
4.4 Conclusions and Perspectives
References
Chapter 5: Visible Light Mediated Cycloaddition Reactions
5.1 Introduction
5.2 [2+2] Cycloadditions: Formation of Four-Membered Rings
5.3 [3+2] Cycloadditions: Formation of Five-Membered Rings
5.4 [4+2] Cycloadditions: Formation of Six-Membered Rings
5.5 Conclusion
References
Chapter 6: Metal-Free Photo(redox) Catalysis
6.1 Introduction
6.2 Applications of Organic Photocatalysts
6.3 Conclusion and Outlook
References
Chapter 7: Visible Light and Copper Complexes: A Promising Match in Photoredox Catalysis
7.1 Introduction
7.2 Photophysical Properties of Copper Catalysts
7.3 Application of Copper Based Photocatalysts in Organic Synthesis
7.4 Outlook
Acknowledgment
References
Chapter 8: Arene Functionalization by Visible Light Photoredox Catalysis
8.1 Introduction
8.2 Applications of Aryl Diazonium Salts
8.3 Photoinduced Ullmann C−N Coupling
8.4 Conclusion
References
Chapter 9: Visible-Light Photocatalysis in the Synthesis of Natural Products
References
Chapter 10: Dual Photoredox Catalysis: The Merger of Photoredox Catalysis with Other Catalytic Activation Modes
10.1 Introduction
10.2 Merger of Photoredox Catalysis with Organocatalysis
10.3 Merger of Photoredox Catalysis with Acid Catalysis
10.4 Merger of Photoredox Catalysis with Transition Metal Catalysis
10.5 Conclusions
References
Chapter 11: Enantioselective Photocatalysis
11.1 Introduction
11.2 The Twentieth Century: Pioneering Work
11.3 The Twenty-First Century: Contemporary Developments
11.4 Conclusions and Outlook
References
Chapter 12: Photomediated Controlled Polymerizations
12.1 Catalyst Activation by Light
12.2 Chain-End Activation by Light
12.3 Conclusions
References
Chapter 13: Accelerating Visible-Light Photoredox Catalysis in Continuous-Flow Reactors
13.1 Introduction
13.2 Homogeneous Photocatalysis in Single-Phase Flow
13.3 Gas–liquid Photocatalysis in Flow
13.4 Heterogeneous Photocatalysis in Flow
13.5 Conclusions
Conflict of Interest
References
Chapter 14: The Application of Visible-Light-Mediated Reactions to the Synthesis of Pharmaceutical Compounds
14.1 Introduction
14.2 Asymmetric Benzylation
14.3 Amide Bond Formation
14.4 C−H Azidation
14.5 Visible-Light-Mediated Benzothiophene Synthesis
14.6 α-Amino Radical Functionalization
14.7 Visible-Light-Mediated Radical Smiles Rearrangement
14.8 Photoredox and Nickel Dual Catalysis
14.9 The Scale-Up of Visible-Light-Mediated Reactions Via Continuous Processing
References
Index
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