Details

Name Reactions for Homologation, Part 1


Name Reactions for Homologation, Part 1


Comprehensive Name Reactions, Band 5 1. Aufl.

von: Jie Jack Li, E. J. Corey

168,99 €

Verlag: Wiley
Format: PDF
Veröffentl.: 04.05.2009
ISBN/EAN: 9780470487013
Sprache: englisch
Anzahl Seiten: 732

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Beschreibungen

<p>"A valuable addition to the literature by any measure and surely will prove its merit in years to come. The new knowledge that arises with its help will be impressive and of great benefit to humankind."<br />—<b>From the Foreword by E. J. Corey</b>, Nobel Prize Laureate</p> <p><b>An invaluable guide to name reactions and reagents for homologations</b></p> <p>Name Reactions for Homologations, Part I of Wiley's Comprehensive Name Reactions series comprises a comprehensive treatise on name reactions for homologations. With contributions from world-recognized authorities in the field, this reference offers an up-to-date, concise compilation of the most commonly used and widely known name reactions and reagents. <i>Part I</i> discusses Organometallics, Carbon-chain Homologation, and Radical Chemistry.</p> <p>Arranged alphabetically by name reactions, the listing provides:</p> <ul> <li>Description of the reaction</li> <li>Historical perspective</li> <li>A mechanism for the reaction</li> <li>Variations and improvements on the reaction</li> <li>Synthetic utilities of the reaction</li> <li>Experimental details</li> <li>References to the current primary literature</li> </ul> <p>Armed with this invaluable resource, both students and professionals will have at their fingertips a comprehensive guide to important mechanisms and phenomena in homologation.</p>
Foreword. <p>Preface.</p> <p>Contributing Authors.</p> <p><b>Chapter 1: Organometallics.</b></p> <p>Section 1.1 Palladium Chemistry.</p> <p>Section 1.2 Organocopper Reagents.</p> <p>Section 1.3 Other Organometallic Reagents.</p> <p><b>Chapter 2: Carbon-Chain Homologations.</b></p> <p>2.1 Arndt-Eistert homologation.</p> <p>2.2 Morita-Baylis-Hillman reaction.</p> <p>2.3 Benzoin condensation.</p> <p>2.4 Corey-Fuchs reaction.</p> <p>2.5 Henry reaction.</p> <p>2.6 Horner-Wadsworth-Emmons reaction.</p> <p>2.7 Julia-Lythgoe olefination.</p> <p>2.8 Knoevenagel condensation.</p> <p>2.9 Mukaiyama aldol reaction.</p> <p>2.10 Peterson olefination.</p> <p>2.11 Sakurai allylation reaction.</p> <p>2.12 Stetter reaction.</p> <p>2.13 Wittig reaction.</p> <p><b>Chapter 3: Radical Chemistry.</b></p> <p>3.1 Barton-McCombie deoxygenation.</p> <p>3.2 Barton nitrite photolysis.</p> <p>3.3 Sandmeyer reaction.</p> <p>3.4 Wohl-Ziegler reaction.</p> <p>Appendixes.</p> <p>Appendix 1, Table of Contents for Volume 1: Name Reactions in Heterocyclic Chemistry.</p> <p>Appendix 2, Table of Contents for Volume 2: Name Reactions for Functional Group Transformations.</p> <p>Appendix 3, Table of Contents for Volume 4: Name Reactions for Homologations-2.</p>
Applied Organometallic Chemistry
<b>Jie Jack Li</b> is a chemist at Bristol-Myers Squibb Company. He received his BS from Nanjing University and his PhD in organic chemistry at Indiana University. Dr. Li completed a postdoctoral fellowship at MIT. He is coauthor of various books, including <i>Name Reactions in Heterocyclic Chemistry</i>, <i>Contemporary Drug Synthesis</i>, <i>Name Reactions for Functional Group Transformations</i>, <i>Name Reactions for Homologations, Parts I and II</i>, <i>Name Reactions on Ring Formations</i>, and <i>The Art of Drug Synthesis</i>, all published by Wiley.
"Jack Li and his illustrious team of chemists have done it again. It is hard to imagine how one could organize and categorize a topic so broad as "homologation" reactions. These are some of the bread and butter transforms of organic chemistry ? reactions that are fundamentally important to the practice of chemical synthesis. This two book series is masterfully organized and easy to use both as a reference work for the classroom and a springboard for practitioners to rapidly apply these reactions in the laboratory. The extensive coverage of these critical reactions, including a historical perspective, mechanism, synthetic utility, and actual experimental details will ensure that these books will be on the shelf of every serious organic chemist for years to come." <p>--Phil S. Baran, The Scripps Research Institute</p>

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