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Materials Nanoarchitectonics


Materials Nanoarchitectonics


1. Aufl.

von: Katsuhiko Ariga, Mitsuhiro Ebara

133,99 €

Verlag: Wiley-VCH
Format: PDF
Veröffentl.: 15.01.2018
ISBN/EAN: 9783527808281
Sprache: englisch
Anzahl Seiten: 328

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Beschreibungen

A unique overview of the manufacture of and applications for materials nanoarchitectonics, placing otherwise hard-to-find information in context. Edited by highly respected researchers from the most renowned materials science institute in Japan, the first part of this volume focuses on the fabrication and characterization of zero to three-dimensional nanomaterials, while the second part presents already existing as well as emerging applications in physics, chemistry, biology, and biomedicine.
1 Change Thinking toward Nanoarchitectonics 1Katsuhiko Ariga andMasakazu Aono 1.1 From Nanotechnology to Nanoarchitectonics 1 1.2 Way of Nanoarchitectonics 2 1.3 Materials Nanoarchitectonics 3 References 4 Part I Zero- and One-Dimensional Nanoarchitectonics 7 2 Architectonics in Nanoparticles 9Qingmin Ji, Xinbang Liu, and Ke Yin 2.1 Introduction 9 2.2 Soft Nanoparticles 10 2.2.1 Smart Polymer Nanoparticles 10 2.2.1.1 Multi-Responsive Polymer Nanoparticles for Biological Therapy 10 2.2.1.2 Optoelectrical Polymer Nanoparticles 12 2.2.2 Nanoparticles from Biomimetic Assembly 13 2.3 Hierarchical Architecturing of Solid Nanoparticles 15 2.3.1 Porous Nanoparticles 15 2.3.2 Layered Nanoparticles 19 2.4 Janus (Asymmetric) Nanoparticles 21 2.5 Functional Architectures on the Surface of Nanoparticles 23 2.6 Summary 24 References 25 3 Aspects of One-Dimensional Nanostructures: Synthesis, Characterization, and Applications 33Amit Dalui, Ali Hossain Khan, Bapi Pradhan, Srabanti Ghosh, and Somobrata Acharya 3.1 Introduction 33 3.2 Synthesis of NCs 35 3.2.1 Organometallic Synthesis Method 37 3.2.2 Single-Source Molecular Precursor Methods 37 3.2.3 Solvothermal/HydrothermalMethods 39 3.2.4 Template-Assisted Growth Methods 39 3.3 Growth Mechanisms of 1D Nanocrystals 40 3.3.1 Solution–Liquid–Solid (SLS) Growth Approach 40 3.3.2 Oriented Attachment Growth Mechanism 40 3.3.3 Kinetically Induced Anisotropic Growth 42 3.3.3.1 Surface Energy and Selective Ligand Adhesion 42 3.3.3.2 Influence of the Phase of the Crystalline Seed Materials 43 3.3.3.3 Interplay betweenThermodynamic or Kinetic Growth Regimes 43 3.4 Post-SyntheticModification 44 3.4.1 Post-Synthetic Surface Modification 44 3.4.2 Post-Synthetic Chemical Transformation of NCs 47 3.5 Essential Characterization Techniques 48 3.6 Promising Applications of 1D NCs 50 3.6.1 Optical Polarization 50 3.6.2 Field-Effect Transistors 54 3.6.3 Photovoltaic Applications 57 3.6.4 Photodetection and Sensing 60 3.6.5 Catalysis 62 3.7 Summary and Conclusions 65 References 66 4 Tubular Nanocontainers for Drug Delivery 85Yusuf Darrat, Ekaterina Naumenko, Giuseppe Cavallaro, Giuseppe Lazzara, Yuri Lvov, and Rawil Fakhrullin 4.1 Introduction 85 4.2 Carbon Nanotubes for Drug Delivery 86 4.2.1 Characteristics of Carbon Nanotubes 86 4.2.2 Functionalization of CNTs for Drug Delivery 87 4.2.3 Uptake of Carbon Nanotubes 87 4.2.4 Hybrid Materials 88 4.2.5 Vaccine Treatment 89 4.2.6 Cancer Treatment 90 4.2.7 Gene Therapy 90 4.2.8 Toxicity 90 4.3 Halloysite-Nanotube-Based Carriers for Drug Delivery 91 4.3.1 Halloysite Nanotubes: A Biocompatible Clay with Drug Delivery Capacity 91 4.3.2 Modified Halloysite Nanotubes with a Time-Extended Effect on the Drug Release 91 4.3.3 Covalently Functionalized Halloysite Nanotubes as Drug Delivery Systems Sensitive to Specific External Stimuli 93 4.3.4 Hybrids Based on Halloysite Nanotubes as Dual Drug Delivery Systems 94 4.4 Tubular Nanosized Drug Carriers: Uptake Mechanisms 95 4.5 Conclusions 100 References 102 Part II Two-Dimensional Nanoarchitectonics 109 5 Graphene Nanotechnology 111Katsunori Wakabayashi 5.1 Introduction 111 5.2 Electronic States of Graphene 112 5.3 Graphene Nanoribbons and Edge States 112 5.4 Spintronic Properties of Graphene 115 5.4.1 Electric Field Induced Half-Metallicity 117 5.5 Summary 119 References 120 6 Nanoarchitectonics of Multilayer Shells toward Biomedical Application 125Wei Cui and Junbai Li 6.1 Introduction 125 6.2 Hollow-Structured Multilayers 126 6.3 Multilayer Shells on Template 130 6.4 Summary and Outlook 135 Acknowledgments 135 References 136 7 Layered Nanoarchitectonics with Layer-by-Layer Assembly Strategy for Biomedical Applications 141Wei Qi and Jing Yan 7.1 Layer-by-Layer Assembly Technique 142 7.1.1 Basics of LbL 142 7.1.2 Dipping Coating 142 7.1.3 Spin Coating 143 7.1.4 Spray Coating 144 7.2 LbL-Assembled Layer Architectures with Tunable Properties 144 7.3 The Application of the LbL-Assembled Layer Architectures in Biomedicine 146 7.3.1 Biosensing 146 7.3.2 Drug Delivery 148 7.3.3 Cellular and Tissue Engineering 148 7.4 Summary and Outlook 149 Acknowledgment 150 References 150 8 Emerging 2D Materials 155Ken Sakaushi 8.1 Introduction 155 8.2 Revisiting Uniqueness of Graphene as the Archetype of 2D Materials Systems 155 8.3 Emerging 2D Materials 158 8.4 Remarks 162 Acknowledgment 162 References 162 Part III Three-Dimensional and Hierarchic Nanoarchitectonics 165 9 Self-Assembly and Directed Assembly 167Hejin Jiang, Yutao Sang, Li Zhang, andMinghua Liu 9.1 Introduction 167 9.2 Amphiphile Self-Assembly 169 9.3 ?-Conjugated Molecule Self-Assembly 170 9.4 Peptide Self-Assembly 172 9.5 Self-Assembly of Block Polymers 173 9.5.1 Directed Self-Assembly (DSA) of BCPs 173 9.5.2 Magnetic Fields Directing the Alignment of BCPs 175 9.6 DNA-Directed Self-Assembly 176 9.7 Directed Self-Assembly of Nanoparticles 179 9.8 LB-Technique-Directed Alignment of Nanostructures 181 9.9 Conclusions 182 References 183 10 Functional Porous Materials 187Watcharop Chaikittisilp 10.1 Introduction 187 10.2 Classification of Porous Materials 188 10.3 Functional Frameworks: from Inorganic, through Organic, to Inorganic–Organic 190 10.4 Summary and Outlook 195 References 196 11 Integrated Composites and Hybrids 199Shenmin Zhu, Hui Pan, and Mengdan Xia 11.1 3D Hybrid Nanoarchitectures Assembled from 0D and 2D Nanomaterials 199 11.2 3D Hybrid Nanoarchitectures Assembled from 1D and 2D Nanomaterials 201 11.3 3D Hybrid Nanoarchitectures Assembled from 2D and 2D Nanomaterials 203 11.4 Other Approaches to 3D Hybrid Nanoarchitectures 205 11.5 Conclusion 207 References 208 12 Shape-MemoryMaterials 209Koichiro Uto 12.1 Introduction 209 12.2 Fundamentals of Shape-Memory Effect in Polymers 211 12.3 Categorization of Shape-Memory Polymers on the Basis of Nanoarchitectonics 212 12.4 Shape-Memory Polymers with Different Architectures 213 12.5 New Directions in the Field of Shape-Memory Polymers 216 12.6 Conclusions 217 References 219 Part IV Materials Nanoarchitectonics for Application 1: Physical and Chemical 221 13 Optically Active Organic Field-Effect Transistors 223YutakaWakayama 13.1 Introduction 223 13.2 Phototransistors 224 13.2.1 Single-Crystal-Based and Nanowire-Based Phototransistors 224 13.2.2 Thin-Film-Based Phototransistors 226 13.3 Photochromism in OFETs 227 13.3.1 Interface Engineering 228 13.3.2 Doping in Channel/Dielectric Layers 229 13.3.3 PhotochromicThin Film as Transistor Channel 230 13.3.4 Laser Patterning of Electric Circuits 232 13.4 Summary and Perspectives 235 References 236 14 Efficient Absorption of Sunlight Using Resonant Nanoparticles for Solar Heat Applications 241Satoshi Ishii, Kai Chen, Ramu P. Sugavaneshwar, Hideo Okuyama, Thang D. Dao, Satish L. Shinde,Manpreet Kaur,Masahiro Kitajima, and Tadaaki Nagao 14.1 Introduction 241 14.2 Electromagnetic Analysis for Finding the Resonance Conditions of Nanoparticles 243 14.3 Plasmon Resonance Nanoparticles for Sunlight Absorption 243 14.3.1 Analytical Calculations 243 14.3.2 Experiments 245 14.4 Mie Resonance Nanoparticles for Sunlight Absorption 246 14.4.1 Analytical Calculations 246 14.4.2 Experiments 247 14.5 Applications of Resonant Nanoparticles 249 14.6 Summary 250 Acknowledgments 251 References 251 15 Nanoarchitectonics Approach for Sensing 255Katsuhiko Ariga 15.1 Introduction 255 15.2 Layered Mesoporous Carbon Sensor 256 15.3 Layered Graphene Sensor 257 15.4 Hierarchic Carbon Capsule Sensor 258 15.5 Cage-in-Fiber Sensor 260 15.6 Summary 262 References 262 16 Self-Healing 265Takeshi Sato andMitsuhiro Ebara 16.1 Introduction 265 16.2 History of Self-Healing Materials 266 16.3 Dynamic Cross-links to Construct a Self-Healing Hydrogel Network 267 16.3.1 Host–Guest Interactions 267 16.3.2 Electrostatic Interactions 268 16.3.3 Metal–Ligand Interactions 268 16.4 Further Applications of Self-Healing Materials 269 16.4.1 Medical Applications 269 16.4.2 Application for Engineering 271 16.5 Conclusion 273 References 273 Part V Materials Nanoarchitectonics for Application 2: Biological and Biomedical 277 17 Materials Nanoarchitectonics: Drug Delivery System 279Yohei Kotsuchibashi 17.1 Introduction 279 17.1.1 Diagnosis from Tissues to the Organelles Using Nanomaterials 279 17.1.2 Current Thermoresponsive Drug Carriers 281 17.1.3 Smart Nanocarriers for Benzoxaborole-Based Drugs 284 17.2 Conclusion and Future Trends 287 References 287 18 Mechanobiology 291Jun Nakanishi 18.1 Introduction 291 18.2 Micropatterning Cellular Shape and Cluster Geometry 292 18.3 Dynamic Micropatterning Single Cells and Cell Collectives 294 18.4 Nanopatterning Cell–Extracellular Matrix Interactions 297 18.5 Concluding Remarks 299 References 300 19 Diagnostics 303Mitsuhiro Ebara 19.1 Introduction 303 19.2 Immunoassays 304 19.3 Nucleic Acid Tests 306 19.4 Stimuli-Responsive Biomarker Separations 306 19.5 Stimuli-Responsive Diagnostics in the DevelopingWorld 308 19.6 Conclusions 309 References 310 20 Immunoengineering 313Yasuhiro Nakagawa andMitsuhiro Ebara 20.1 Introduction 313 20.2 Immunoevasive Biomaterials 314 20.3 Immune-Activating Biomaterials 318 20.4 Immunosuppressive Biomaterials 321 20.5 Conclusions 324 References 324 Index 327
Dr. Katsuhiko Ariga is the Director of Supermolecules Unit and Principal Investigator of World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), the National Institute for Materials Science (NIMS), Japan. He received his B.Eng., M.Eng., and Ph.D. degrees from the Tokyo Institute of Technology (TIT). He was Assistant Professor at TIT, worked as a postdoctoral fellow at the University of Texas at Austin, USA, and then served as a group leader in the Supermolecules Project at Japan Science and Technology Agency (JST). Thereafter, Dr. Ariga worked as Associate Professor at the Nara Institute of Science and Technology, and then became involved with the ERATO Nanospace. Dr. Mitsuhiro Ebara is Principal Investigator in the Mechanobiology Group at the National Institute for Materials Science (NIMS), Japan.
A unique overview of the manufacture of and applications for materials nanoarchitectonics, placing otherwise hard-to-find information in context. Edited by highly respected researchers from the most renowned materials science institute in Japan, the first part of this volume focuses on the fabrication and characterization of zero to three-dimensional nanomaterials, while the second part presents already existing as well as emerging applications in physics, chemistry, biology, and biomedicine.

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