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<b>Chapter One LIGANDS FOR WATER-SOLUBILIZING ORGANOMETALLIC COMPOUNDS.</b> <p>1. (<i>Meta</i>-Sulfonatophenyl)Diphenylphosphine, Sodium Salt and Its Complexes with Rhodium(I), Ruthenium(II), Iridium(1).</p> <p>2. Syntheses of Water-Soluble Phosphines and Their Transition Metal Complexes.</p> <p>3. Tris[Tris(Sodium <i>m</i>-sulfonatophenyl)phosphino] Palladium(0)-Enneahydrate.</p> <p>4. Sulfonated Phosphines.</p> <p>5. (S,S)-2,3-Bis[Di(<i>m</i>-Sodiumsulfonatophenyl)phosphino]butane-(chiraphos_TS) and (S,S)-2,4-Bis[di(<i>m</i>-Sodiumsulfonatophenyl)-phosphinolpentane (BDPP_TS).</p> <p>6. 1,3,5-Triaza-7-phosphatricyclo[3.3.1.1^3,7]decane and Derivatives.</p> <p><b>Chapter Two BIOMIMETIC AND SPECIAL PROPERTY LIGANDS.</b></p> <p>7. 2.2':6',2"-Terpyridine.</p> <p>8. Poly(1-pyrazolyl)alkane Ligands.</p> <p>9 . Tris[<i>N</i>-(3-<i>tert</i>-butyl)pyrazolyl]methane.</p> <p>10. Tris[2-(1,4-Diisopropylimidazolyl)]phosphine.</p> <p>11. Tris[(2-pyridyl)methyl]amine (TPA) and (+)-Bis[(2-pyridyl)-methyl]-l-(2-pyridyl)ethylamine (a-MeTPA).</p> <p>12. C₂-Symmetric 1,4-Diisopropyl-7-<i>R</i>-l,4,7-Triazacyclononanes.</p> <p>13. <i>N</i>-(2-hydroxyethyl)-3,5-Dimethylpyrazole, a Dinuclear Copper Complex, and <i>N</i>-(2-<i>p</i>-Toluenesulfonylethyl)-3,5-dimethy-pyrazole.</p> <p>14. <i>N</i>-(2-Mercaptoethyl)-3,5-dimethylpyrazole.</p> <p>15. 1,5-Diazacyclooctane, Pendant Arm Thiolato Derivatives and [<i>N</i>,<i>N</i>'-Bis(2-Mercaptoethyl)-1,5-Diazacyclooctanato]-nickel(II).</p> <p>16. Polydentate Thiolate and Selenolate Ligands, RN(CH₂,CH₂,S(Se)^-)₂, and Their Dimeric and Mononuclear Ni(II) Complexes.</p> <p>17. Poly[(methylthio)methyl]borates and Representative Metal Derivative.</p> <p>18. Polyaza Binucleating Ligands: OBISTREN and OBISDIEN.</p> <p>19. <i>N</i>,<i>N</i>'.bis(2-hydroxybyl.thylenediamine-<i>N</i>,<i>N</i>'-diacetic acid (HBED).</p> <p>20. <i>N-Tert</i>-Alkyl-Anilides as Bulky Ancillary Ligands.</p> <p>21. 1,2-Bis(Dichlorophosphino)-1,2-Dimethylhydrazine and Alkoxy/Aryloxy Derivatives.</p> <p>22. Tris[(<i>tert</i>-butylamino)-dimethylsilyl]methylsilane and Its Precursors.</p> <p><b>Chapter Three TRANSITION METAL COMPLEXES AND PRECURSORS.</b></p> <p>23. Facile Synthesis of Isomerically Pure.</p> <p>24. <i>cis</i>-Bis(benzeneacetonitrile)dichloroplatinum(II) and <i>trans</i>-Bis(benzeneacetonitrile)dichloroplatinum(II).</p> <p>25. Platinum(II) Complexes of Dimethyl Sulfide.</p> <p>26. (2,2' :6',2"-Terpyridine) Methylplatinurn(II) Chloride and (l,l0-Phenanthroline)methylchloroplatinum(II).</p> <p>27. (<i>N</i>,<i>N</i>-Chelate)(olefin)platinum(0) Complexes.</p> <p>28. Dimethylpalladium(II) and Monomethylpalladium(II) Reagents and Complexes.</p> <p>29. 2,4-Pentanedionatogold(I) Complexes and 2,4-Pentanedionatothallium.</p> <p>30. Tetrakis(Pyridine)SiIver(2 + )Peroxydisulfate.</p> <p>31. One-Pot Synthesis of Tetrahydronium Tris(4,4'-Dicarboxylato-2,2'-Bipyridine)ruthenium(II) Dihydrate.</p> <p>32. Trichloro[2,2' :6,2"-Terpyridine]ruthenium(III) and Phosphine Ligand Derivatives.</p> <p>33. Monomeric Tetrahydrofuran-Stabilized Molybdenum(III) Halides.</p> <p>34. Facial Molybdenum(lI1) Triamine Complexes.</p> <p>35. High-Valent Mono-(5-Pentamethylcyclopentadienyl)vanadium and Molybdenum Complexes.</p> <p>36. Monoindenyltrichloride Complexes of Titanium(IV), Zirconium(IV), and Hafnium(IV).</p> <p>37. Labile Copper(I) Chloride Complexes: Preparation and Handling.</p> <p><b>Chapter Four MAIN GROUP AND TRANSITION METAL CLUSTER COMPOUNDS.</b></p> <p>38. 7,8-Dicarbaundecaborane(13).</p> <p>39. Borazine, Polyborazylene, B-Vinylborazine and Poly(B-Vinylborazine).</p> <p>40. Transition Metal Complexes of the Lacunary Heteropolytungstate, [P₂W₁₇O₆₁] ^10-.</p> <p>41. Bis(Triphenylphosphorany1idene)A mmonium µ-Carbonyl-1kC:2kC-Decacarbonyl-1k³C,2k³,3k⁴C-µ-Hydrido-1k:2k-triangubTriruthenate(1—).</p> <p>42. Dipotassium Undecacarbonyl Trimetallate(2—) Clusters, K₂[M₃(CO)₁₁] (M = Ru, Os).</p> <p>43. [PPN]₂[Ru₃(CO)₁₁] and [PPN]₂[OS₃(CO)₁₁], µ-Nitrido-Bis(Triphenylphosphorus) (1 +) Undecacarbonyltriruthenate (2 —) and Undecacarbonyltriosmate(2 —).</p> <p>44. Platinum-Ruthenium Carbonyl Cluster Complexes.</p> <p>45. Tri(µ-carbonyl)nonacarbonyltetrarhodiu.</p> <p>46. High Nuclearity Hydridodecaruthenium Clusters.</p> <p><b>Chapter Five MAIN GROUP AND TRANSITION METAL HYDRLDES.</b></p> <p>47. Dichlorodihydro(<i>N</i>,<i>N</i>,<i>N'</i>,<i>N</i>,-Tetraethyl-1,2-ethanediamine-<i>N</i>,<i>N'</i>)silicon.</p> <p>48. Tricarbonyl(hydrido)[1,2-bis(diphenylphosphino)ethane]-manganese as Precursor to Labile Site Derivatives.</p> <p>49. Pentahydridobis(tricyclohexylphosphine)iridium(V) and trihydridotris (triphenylphosphine)iridium(III).</p> <p><b>Chapter Six TITANIUM(1II) CHLORIDE.</b></p> <p>(A Correction to Inorganic Syntheses, Vol. 24, pp. 181 (1986).</p> <p>50. An Active Form of Titanium(II1) Chloride.</p> <p>Contributor Index.</p> <p>Subject Index.</p> <p>Formula Index.</p> <p>Chemical Abstracts Service Registry Number Index.</p>

<p><b>Dr. Marcetta York Darensbourg</b> is an American inorganic chemist. She is a Distinguished Professor of Chemistry at Texas A&M University. Her current work focuses on iron hydrogenases and iron nitrosyl complexes.</p>

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