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Metallosurfactants

From Fundamentals to Catalytic and Biomedical Applications
1. Aufl.

von: Surinder K. Mehta, Ravneet Kaur
133,99 €
Verlag:	Wiley-VCH
Format:	PDF
Veröffentl.:	29.12.2021
ISBN/EAN:	9783527831272
Sprache:	englisch
Anzahl Seiten:	288

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Titelbeschreibung

Metallosurfactants Provides up-to-date coverage of the synthesis, properties, and applications of metallosurfactants Metallosurfactants: From Fundamentals to Catalytic and Biomedical Applications is a thorough introduction to amphiphilic compounds that allow to incorporate metal ions in the surfactant system. This comprehensive reference and guide describes the fundamentals of metal surfactant complexes, highlights recent advances in the field, and explores current and future applications and research areas. Gradually progressing from basic to advanced topics, the authors first explain the classification and characterization of metallosurfactants before delving into more complex concepts and various catalytic, sensing, and biomedical applications. The book begins with coverage of the synthesis of metallosurfactants and their surface, interfacial, and aggregation behavior. Subsequent chapters discuss applications of metallosurfactants in areas such as drug delivery, molecular machines, transfection, nanoparticle synthesis, and carbon monoxide-releasing molecules (CORMs). Other topics include the use of metallosurfactants as catalysts in organic reactions, and as anticancer and antimicrobial agents in drug delivery and formulation. This unique reference <ul><li>Provides an overview of the structure-function relationship, synthesis methods, and characterization of metallosurfactants </li> <li>Reviews current trends in metallosurfactant development and research</li> <li>Examines the use of metallosurfactants in a wide range of reactions, including esterolytic reactions and hydrogen generation</li> <li>Discusses advanced applications of metallosurfactants, e.g. as nanoreactors for nanoparticle synthesis, non-viral transfection vectors, and sensors</li></ul> Metallosurfactants: From Fundamentals to Catalytic and Biomedical Applications is an excellent introduction to the growing field of metallosurfactant chemistry as well as a concise, highly useful reference for researchers and scientists in both academia and industry.

Inhaltsverzeichnis

Preface xi 1 Metallosurfactants, a “Novel Portmanteau”: A Holistic Insight into the Structural–Physiognomies Relationships, Synthesis Stratagems, and Characterization 1 Ankush Parmar, Shilpee Sachar, and Shweta Sharma 1.1 Introduction 1 1.2 Intrinsic Physiognomies of Metallosurfactants 3 1.3 Classification of Metallosurfactants 6 1.4 Syntheses Stratagems and Characterization of Metallosurfactants 8 1.4.1 Metathesis Reaction 8 1.4.2 Ligand Substitution Reaction 9 1.4.3 Ligand Insertion Reaction 10 1.5 Conclusion 10 References 14 2 Metallosurfactants: A Surface and Interface Perspective 21 Ravneet Kaur, Neena Mehta, and Surinder K. Mehta 2.1 Introduction 21 2.2 Micellization and Surface Parameters 22 2.2.1 Thermodynamics of Micellization 23 2.2.2 Adsorption Parameters 24 2.3 Adsorption of Surfactant Monolayers 34 2.4 Conclusions 36 References 36 3 Metallosurfactant Self-Assembly: Structures and Chemistry of Interfacial, Biphasic, and Phase Transfer Catalysis 39 Ravneet Kaur and Aashima Sharma 3.1 Introduction 39 3.2 Self-Aggregation Behavior 40 3.2.1 Micelles 40 3.2.2 Inverted Micelles 44 3.2.3 Vesicles 46 3.2.4 Lamellar Phases 49 3.3 Chemistry of Catalysis 50 3.3.1 Micellar Catalysis 51 3.3.2 Vesicular Structures in Catalysis 53 3.3.3 Interfacial Catalysis 56 3.4 Conclusions 58 Acknowledgment 58 References 58 4 Hydrolytic Metallosurfactants: Nanocatalysts for Esterolytic Reactions 63 Bhanushree Gupta, Rahul Sharma, and Kallol K. Ghosh 4.1 Introduction 63 4.2 Metallosurfactants as Nanocatalyst for Esterolytic Reactions 64 4.3 Catalytic Hydrolysis of Carboxylate Esters 65 4.4 Catalytic Hydrolysis of Phosphate Esters 70 4.5 Quantitative Treatment of Observed Rates: Application of Kinetic Models 77 4.6 Conclusion 78 References 79 5 Metallosurfactants as Catalysts in Organic Reactions and Energy-Based Applications 83 Sakshi Goel and Supriya Rana 5.1 Introduction 83 5.2 Metallosurfactants as Catalysts in Organic Reactions 85 5.2.1 Types of Reactions 85 5.2.2 NHC Metallosurfactant-Catalyzed Reactions 88 5.2.3 Stimuli-Responsive Metallosurfactant-Catalyzed Reactions 89 5.2.4 Miscellaneous Reactions 90 5.3 Metallosurfactants as Catalyst in Water Oxidation 91 5.4 Light-Driven Hydrogen Generation 95 5.5 Conclusions 97 References 98 6 Metallosurfactants as Drug-Delivery Vehicles 103 Rohini Kanwar, Amit Kumar, Jyoti Rathee, and Surinder K. Mehta 6.1 Introduction 103 6.2 Distinct Assemblies of Metallosurfactants in Drug Delivery 105 6.2.1 Metallosomes as Drug-Delivery Agents 105 6.2.2 Metallosurfactants and Its Self-Assembled Structures as Nanovectors 107 6.2.3 Metallosurfactant Co-polymer-Based Micellar Systems for Drug Delivery 108 6.3 Metallosurfactants as MRI Contrast Agents 109 6.4 Conclusion 112 Acknowledgments 112 References 112 7 Metallosurfactants as Molecular Machines for the Preparation of Hybrid Silica-Based Porous Material 117 Rekha Bhar and Surinder K. Mehta 7.1 Introduction 117 7.2 Porous Silica-Based Materials 118 7.2.1 Molecular Machine 119 7.2.2 General Synthesis Procedure of Porous Silica Material 120 7.3 Different Types of Porous Silica-Based Material 121 7.3.1 Copper@Surfactants-Based Porous Material 121 7.3.2 Ruthenium@Surfactants-Based Porous Material 124 7.3.3 Cobalt@Surfactants-Based Porous Material 125 7.3.4 Iron@Surfactants-Based Porous Material 126 7.3.5 Other Metallosurfactant-Based Porous Material 128 7.4 Future Perspectives 129 7.5 Conclusion 130 References 130 8 Metallosurfactants as Non-viral Vectors in Transfection 135 Pilar López-Cornejo, José A. Lebrón, Francisco J. Ostos, Manuel López-López, María L. Moyá, Eva Bernal, and Carmen Martín 8.1 Introduction 135 8.2 Metallosurfactant Monomers 137 8.3 Metallomicelles 145 8.4 Metalloliposomes (Metallosomes) 147 8.5 Future Perspectives 151 Acknowledgments 151 References 151 9 Metallosurfactants as Nanoreactors for Nanoparticle Synthesis 159 Jaspreet Kaur, Rekha Bhar, Khushwinder Kaur, and Surinder K. Mehta 9.1 Introduction 159 9.2 Metallosurfactants as Reactors for Nanoparticle Synthesis 161 9.2.1 Colloidal Synthesis 161 9.2.2 Thermal Decomposition 168 9.2.3 Biphasic Redox Reaction 169 9.3 Future Perspective 173 9.4 Conclusion 174 Acknowledgments 174 References 174 10 Metallosurfactants and Their Biological Attributes: Anticancer and Antimicrobial Properties 179 Neha Jindal and Shivani Uppal 10.1 Introduction 179 10.2 Antimicrobial Activity 180 10.2.1 Metallosurfactants Effective against Bacteria 181 10.2.2 Metallosurfactants Effective Against Fungus 182 10.3 Anticancer Activity 185 10.3.1 Metallosurfactants Effective Against Breast Cancer 186 10.3.2 Metallosurfactants Effective Against Lung Cancer 189 10.4 Conclusion and Future Challenges 189 References 190 11 Metallosurfactants as Carbon Monoxide-Releasing Molecules 195 Maribel Marín-García, Núria Benseny-Cases, Mercedes Camacho, and Ramon Barnadas-Rodríguez 11.1 Why CO? 195 11.2 How to Deliver CO? 198 11.3 CO-releasing Metallosurfactants 202 11.3.1 Synthesis of Molybdenum-Based CORMs 204 11.3.2 Properties of Mixed CORAs Constituted by Molybdenum-Based Metallosurfactants and Phospholipids 205 11.4 Conclusions 208 Acknowledgments 208 References 208 12 Supramolecular Metal-Modified Nanocontainers Based on Amphiphilic and Hybrid Matrix: Self-Assembling Behavior and Practical Applications 223 Elena P. Zhiltsova, Marina R. Ibatullina, Ruslan R. Kashapov, Nadezda E. Kashapova, Albina Y. Ziganshina, Lucia Y. Zakharova, and Oleg G. Sinyashin 12.1 Introduction 223 12.2 Structure, Properties, and Biomedical Application of Metallosurfactants 224 12.3 Amphiphilic System Based on Metallosurfactants and Macrocycles 227 12.4 Nanocomposites Based on Amphiphilic Resorcinarenes and Metal Nanoparticles 235 12.5 Conclusions 239 Acknowledgments 240 References 241 13 Metallosurfactants in Nanoscale Molecular Containers as Sensors 249 Devika Vashisht and Nicole Pamme 13.1 Introduction 249 13.1.1 Metallosurfactants 249 13.2 Metallosurfactants as Nanosized Containers for Self-assembled Molecular Devices 251 13.3 Surfactant Aggregates in Chemical Detection 252 13.4 Self-Assembled Moieties as Fluorescent Sensors 253 13.5 Metallosurfactants and Detection Protocol 255 13.6 Conclusions 262 Acknowledgments 262 References 262 Index 265

Autorenportrait

Surinder K. Mehta, Vice Chancellor, University of Ladakh, and Professor of Chemistry, Panjab University, Chandigarh, India. He has published more than 360 articles in international peer-reviewed journals and is the author of numerous books and book chapters. His research interests include metallosurfactant chemistry, nano electrochemical sensors, synthesis and application of semiconducting nanoparticles, colloidal chemistry, and nanodrug delivery systems. Ravneet Kaur, Adjunct Professor of Chemistry and Physical Science, Ivytech Community College, Indiana, USA. She is the author of numerous scientific publications in the field of metallosurfactants chemistry and is a recipient of the All India UGC Postdoctoral Fellowship in Chemical Sciences at Panjab University, and a DAAD fellowship at Technical University Berlin, Germany, among several others.

Back cover copy

Provides up-to-date coverage of the synthesis, properties, and applications of metallosurfactants Metallosurfactants: From Fundamentals to Catalytic and Biomedical Applications is a thorough introduction to amphiphilic compounds that allow to incorporate metal ions in the surfactant system. This comprehensive reference and guide describes the fundamentals of metal surfactant complexes, highlights recent advances in the field, and explores current and future applications and research areas. Gradually progressing from basic to advanced topics, the authors first explain the classification and characterization of metallosurfactants before delving into more complex concepts and various catalytic, sensing, and biomedical applications. The book begins with coverage of the synthesis of metallosurfactants and their surface, interfacial, and aggregation behavior. Subsequent chapters discuss applications of metallosurfactants in areas such as drug delivery, molecular machines, transfection, nanoparticle synthesis, and carbon monoxide-releasing molecules (CORMs). Other topics include the use of metallosurfactants as catalysts in organic reactions, and as anticancer and antimicrobial agents in drug delivery and formulation. This unique reference <ul><li>Provides an overview of the structure-function relationship, synthesis methods, and characterization of metallosurfactants </li> <li>Reviews current trends in metallosurfactant development and research</li> <li>Examines the use of metallosurfactants in a wide range of reactions, including esterolytic reactions and hydrogen generation</li> <li>Discusses advanced applications of metallosurfactants, e.g. as nanoreactors for nanoparticle synthesis, non-viral transfection vectors, and sensors</li></ul> Metallosurfactants: From Fundamentals to Catalytic and Biomedical Applications is an excellent introduction to the growing field of metallosurfactant chemistry as well as a concise, highly useful reference for researchers and scientists in both academia and industry.