Details

Multilayer Thin Films

Sequential Assembly of Nanocomposite Materials
2. Aufl.

von: Gero Decher, Joe B. Schlenoff
367,99 €
Verlag:	Wiley-VCH
Format:	PDF
Veröffentl.:	24.04.2012
ISBN/EAN:	9783527646777
Sprache:	englisch
Anzahl Seiten:	1112

In den Warenkorb

Als Gutschein

DRM-geschütztes eBook, Sie benötigen z.B. Adobe Digital Editions und eine Adobe ID zum Lesen.

Beschreibungen

Titelbeschreibung

This second, comprehensive edition of the pioneering book in this fi eld has been completely revised and extended, now stretching to two volumes. The result is a comprehensive summary of layer-by-layer assembled, truly hybrid nanomaterials and thin fi lms, covering organic, inorganic, colloidal, macromolecular, and biological components, as well as the assembly of nanoscale fi lms derived from them on surfaces. These two volumes are essential for anyone working in the field, as well as scientists and researchers active in materials development, who needs the key knowledge provided herein for linking the field of molecular self-assembly with the bio- and materials sciences.

Inhaltsverzeichnis

VOLUME 1 LAYER-BY-LAYER ASSEMBLY (PUTTING MOLECULES TO WORK) The Whole is More than the Sum of its Parts From Self-Assembly to Directed Assembly History and Development of the Layer-by-Layer Assembly Method LbL-Assembly is the Synthesis of Fuzzy Supramolecular Objects Reproducibility and Choice of Deposition Conditions Monitoring Multilayer Build-up Spray- and Spin-Assisted Multilayer Assembly Recent Developments Final Remarks PART I: Preparation and Characterization LAYER-BY-LAYER PROCESSED MULTILAYERS: CHALLENGES AND OPPORTUNITIES Introduction Fundamental Challenges and Opportunities The Path Forward LAYER-BY-LAYER ASSEMBLY: FROM CONVENTIONAL TO UNCONVENTIONAL METHODS Introduction Conventional LbL Methods Unconventional LbL Methods Summary and Outlook NOVEL MULTILAYER THIN FILMS: HIERARCHIC LAYER-BY-LAYER (HI-LBL) ASSEMBLIES Introduction Hi-LbL for Multi-Cellular Models Hi-LbL for Unusual Drug Delivery Modes Hi-LbL for Sensors Future Perspectives LAYER-BY-LAYER ASSEMBLY USING HOST-GUEST INTERACTIONS Introduction Supramolecular Layer-by-Layer Assembly 3D Patterned Multilayer Assemblies on Surfaces 3D Supramolecular Nanoparticle Crystal Structures Porous 3D Supramolecular Assemblies in Solution Conclusions LBL ASSEMBLIES USING VAN DER WAALS OR AFFINITY INTERACTIONS AND THEIR APPLICATIONS Introduction Stereospecific Template Polymerization of Methacrylates by Stereocomplex Formation in Nanoporous LbL Films Preparation and Properties of Hollow Capsules Composed of Layer-by-Layer Polymer Films Constructed through van der Waals Interactions Fabrication of Three-Dimensional Cellular Multilayers Using Layer-by-Layer Protein Nanofilms Constructed through Affinity Interaction Conclusion LAYER-BY-LAYER ASSEMBLY OF POLYMERIC COMPLEXES Introduction Concept of LbL Assembly of Polymeric Complexes Structural Tailoring of LbL-Assembled Films of Polymeric Complexes LbL-Assembled Functional Films of Polymeric Complexes Summary MAKING AQUEOUS NANOCOLLOIDS FROM LOW SOLUBILITY MATERIALS: LBL SHELLS ON NANOCORES Introduction Formation of Nanocores Ultrasonication-Assisted LbL Assembly Solvent-Assisted Precipitation Into Preformed LbL-Coated Soft Organic Nanoparticles Washless (Titration) LbL Technique Formation of LbL Shells on Nanocores Drug Release Study Conclusions CELLULOSE FIBERS AND FIBRILS AS TEMPLATES FOR THE LAYER-BY-LAYER (LBL) TECHNOLOGY Background Formation of LbLs on Cellulose Fibers The use of LbL to Improve Adhesion between Wood Fibers The Use of LbL to Prepare Antibacterial Fibers The use of NFC/CNC to Prepare Interactive Layers Using the LbL Approach Conclusions FREELY STANDING LBL FILMS Introduction Fabrication of Freely Standing Ultrathin LbL Films Porous and Patterned Freely Standing LbL Films Freely Standing LbL Films with Weak Interactions NEUTRON REFLECTOMETRY AT POLYELECTROLYTE MULTILAYERS Introduction Neutron Reflectometry Preparation Techniques for Polyelectrolyte Multilayers Types of Polyelectrolytes Preparation Parameters Influence of External Fields After PEM Assembly PEM as a Structural Unit Conclusion and Outlook POLYELECTROLYTE CONFORMATION IN AND STRUCTURE OF POLYELECTROLYTE MULTILAYERS Introduction Results Conclusion and Outlook CHARGE BALANCE AND TRANSPORT IN ION-PAIRED POLYELECTROLYTE MULTILAYERS Introduction Association Mechanism: Competitive Ion Pairing Surface versus Bulk Polymer Charge Polyelectrolyte Interdiffusion Ion Transport Through Multilayers: the "Reluctant" Exchange Mechanism Concluding Remarks CONDUCTIVITY SPECTRA OF POLYELECTROLYTE MULTILAYERS REVEALING ION TRANSPORT PROCESSES Introduction to Conductivity Studies of LbL Films PEM Spectra: Overview DC Conductivities of PEMs Modeling of PEM Spectra Ion Conduction in Polyelectrolyte Complexes Scaling Principles in Conductivity Spectra: From Time - Temperature to Time - Humidity Superposition RESPONSIVE LAYER-BY-LAYER ASSEMBLIES: DYNAMICS, STRUCTURE AND FUNCTION Introduction Chain Dynamics and Film Layering Responsive Swellable LbL Films Conclusion and Outlook TAILORING THE MECHANICS OF FREESTANDING MULTILAYERS Introduction Measurements of Mechanical Properties of Flat LbL Films Mechanical Properties of LbL Microcapsules Prospective Applications Utilizing Mechanical Properties DESIGN AND TRANSLATION OF NANOLAYER ASSEMBLY PROCESSES: ELECTROCHEMICAL ENERGY TO PROGRAMMABLE PHARMACIES Introduction Controlling Transport and Storing Charge in Multilayer Thin Films: Ions, Electrons and Molecules LbL Films for Multi-Agent Drug Delivery - Opportunities for Programmable Release Automated Spray-LbL - Enabling Function and Translation Concluding Remarks SURFACE-INITIATED POLYMERIZATION AND LAYER-BY-LAYER FILMS Introduction Overview of Surface-Grafted Polymer Brushes Layer-by-Layer (LbL) Self-Assembly Combined LbL-SIP Approach Applications of the Combined LbL-SIP Approach Concluding Remarks QUARTZ CRYSTAL RESONATOR AS A TOOL FOR FOLLOWING THE BUILD-UP OF POLYELECTROLYTE MULTILAYERS Introduction Basic Concepts Growth Processes Experimental Techniques Analysis of QCR Data VOLUME 2 PART II: Applications ELECTROSTATIC AND COORDINATIVE SUPRAMOLECULAR ASSEMBLY OF FUNCTIONAL FILMS FOR ELECTRONIC APPLICATION AND MATERIALS SEPARATION Introduction Polyelectrolyte Multilayer Membranes Summary and Conclusions OPTOELECTRONIC MATERIALS AND DEVICES INCORPORATING POLYELECTROLYTE MULTILAYERS Introduction Second Order Nonlinear Optics Plasmonic Enhancement of Second Order Nonlinear Optical Response Nonlinear Optical Fibers Optical Fiber Biosensors Antireflection Coatings Electrochromic Devices Electromechanical Actuators NANOSTRUCTURED ELECTRODES ASSEMBLED FROM METAL NANOPARTICLES AND QUANTUM DOTS IN POLYELECTROLYTES Introduction Nanostructured Pt Electrodes from Assemblies of Pt Nanoparticles in Polyelectrolytes Nanostructured Photoelectrodes from Assemblies of Q-CdS in Polyelectrolytes Conclusions RECORD PROPERTIES OF LAYER-BY-LAYER ASSEMBLED COMPOSITES Introduction LbL Assemblies of Clays LBL Assemblies of Carbon Nanotubes Conclusions and Perspectives CARBON NANOTUBE-BASED MULTILAYERS Introduction Characteristics of Carbon Nanotube Layer-by-Layer Assemblies Applications of Carbon Nanotube Layer-by-Layer Assemblies Conclusions NANOCONFINED POLYELECTROLYTE MULTILAYERS: FROM NANOSTRIPES TO MULTISEGMENTED FUNCTIONAL NANOTUBES Introduction Estimation of the Size of Polyelectrolyte Chains in Dilute Solutions Confining LbL Assembly on Flat Surfaces Confining LbL Assembly in Nanopores Conclusions THE DESIGN OF POLYSACCHARIDE MULTILAYERS FOR MEDICAL APPLICATIONS Introduction Polysaccharides as Multilayered film Components: An Overview of Their Structure and Properties Multilayers Formed by Assembly of Weak Polyanions and Chitosan or Chitosan Derivatives Multilayers Formed by Assembly of Strong Polyanions and Chitosan or Chitosan Derivatives Cardiovascular Applications of Polysaccharide Multilayers Conclusions POLYELECTROLYTE MULTILAYER FILMS BASED ON POLYSACCHARIDES: FROM PHYSICAL CHEMISTRY TO THE CONTROL OF CELL DIFFERENTIATION Introduction Film Internal Composition and Hydration Film Cross-Linking: Relation Between Composition and Mechanical Properties Cell Adhesion onto Cross-Linked Films: Cell Adhesion, Cytoskeletal Organization and Comparison with Other Model Materials Cell Differentiation: ESC and Myoblasts Conclusions DIFFUSION OF NANOPARTICLES AND BIOMOLECULES INTO POLYELECTROLYTE MULTILAYER FILMS: TOWARDS NEW FUNCTIONAL MATERIALS Introduction LBL Films in Which Nanoparticles are Incorporated Step-By-Step LBL Films Made Uniquely From Nanoparticles Nanoparticles Produced by Post-treatment of Deposited Films Diffusion of Colloids in Already Deposited Films Emerging Properties of Films Filled with Nanoparticles by the Post-incubation Method Conclusions and Perspectives COUPLING CHEMISTRY AND HYBRIDIZATION OF DNA MOLECULES ON LAYER-BY-LAYER MODIFIED COLLOIDS Introduction Materials and Methods Results Summary A 'MULTILAYERED' APPROACH TO THE DELIVERY OF DNA: EXPLOITING THE STRUCTURE OF POLYELECTROLYTE MULTILAYERS TO PROMOTE SURFACE-MEDIATED CELL TRANSFECTION AND MULTI-AGENT DELIVERY Introduction Surface-Mediated Delivery of DNA: Motivation and Context, Opportunities and Challenges Films Fabricated Using Hydrolytically Degradable Cationic Polymers Toward Spatial Control: Release of DNA from the Surfaces of Implants and Devices Toward Temporal Control: Tunable Release and Sequential Release Concluding Remarks DESIGNING LBL CAPSULES FOR DRUG LOADING AND RELEASE Introduction Engineering Microparticulate Templates to Design LbL Capsules for Controlled Drug Release Engineering the Shell to Design LbL Capsules for Controlled Drug Release Interaction of LbL Capsules with Living Cells In Vitro and In Vivo Conclusions STIMULI-SENSITIVE LBL FILMS FOR CONTROLLED DELIVERY OF PROTEINS AND DRUGS Introduction Avidin-Containing LbL Films Concanavalin A-containing LbL Films Dendrimer-Containing LbL Films Insulin-Containing LbL Films Conclusions ASSEMBLY OF MULTILAYER CAPSULES FOR DRUG ENCAPSULATION AND CONTROLLED RELEASE Introduction Magnetically Sensitive Release Ultrasound-Stimulated Release Photo-Stimulated Release Thermo-Stimulated Release pH-Sensitive Release Redox-Controlled Release Bio-Responsive Release Extension Concluding Remarks ENGINEERED LAYER-BY-LAYER ASSEMBLED CAPSULES FOR BIOMEDICAL APPLICATIONS Introduction Template Selection Material Assembly Loading Degradation and Release Applications Conclusions ASSEMBLY OF POLYMER MULTILAYERS FROM ORGANIC SOLVENTS FOR BIOMOLECULE ENCAPSULATION Introduction Limitations of LbL-Based Biomolecule Encapsulation in Aqueous Phase LbL Biomolecule Encapsulation in the Organic Phase Conclusion and Outlook STIMULI-RESPONSIVE POLYMER COMPOSITE MULTILAYER MICROCAPSULES AND MICROCHAMBER ARRAYS Introduction Fabrication of Stimuli-Responsive LbL Microcapsules Microchamber Arrays Conclusion DOMAIN-CONTAINING FUNCTIONAL POLYELECTROLYTE FILMS: APPLICATIONS TO ANTIMICROBIAL COATINGS AND ENERGY TRANSFER Introduction Polyelectrolyte Films Incorporating Randomly Distributed Hydrophobic Nanodomains for Antimicrobial Applications Multicompartmentalized Stratified Polyelectrolyte Films for Control of Energy Transfer Conclusions and Perspectives CREATING FUNCTIONAL MEMBRANES THROUGH POLYELECTROLYTE ADSORPTION Introduction Functionalization of the Interior of Membranes LBL Films as Membrane Skins Challenges REMOTE AND SELF-INDUCED RELEASE FROM POLYELECTROLYTE MULTILAYER CAPSULES AND FILMS CONTROLLED ARCHITECTURES IN LBL FILMS FOR SENSING AND BIOSENSING Introduction LbL-Based Sensors and Biosensors Special Architectures for Sensing and Biosensing Statistical and Computational Methods to Treat the Data Conclusions and Perspectives PATTERNED MULTILAYER SYSTEMS AND DIRECTED SELF-ASSEMBLY OF FUNCTIONAL NANO-BIO MATERIALS New Approaches and Materials for Multilayer Film Patterning Techniques Cell Adhesion and Patterning Using PEMs PEMs Incorporating Proteins and Their Patterning Metal/Graphene Conductive Patterning via PEM Films Ordered and Disordered Particles on PEMs Mechanical Aspects of PEM Films and Degradable Films ELECTROCHEMICALLY ACTIVE LBL MULTILAYER FILMS: FROM BIOSENSORS TO NANOCATALYSTS 1003 Introduction Electrochemical Response Dynamics of Charge Exchange Conclusions MULTILAYER POLYELECTROLYTE ASSEMBLY IN FEEDBACK ACTIVE COATINGS AND FILMS Introduction. The Concept of Feedback Active Coatings Polyelectrolyte-Based Self-Healing Anticorrosion Coatings Coatings with Antibacterial Activity Conclusions and Outlook

Autorenportrait

Gero Decher is a Distinguished Professor of Chemistry at the University of Strasbourg, France, a senior member of the Institut Universitaire de France (IUF) and a member of the International Center for Frontier Research in Chemistry. His research team is located at CNRS Institut Charles Sadron in Strasbourg where he continues to develop the layer-by-layer assembly method in collaboration with his colleagues Pierre Schaaf and Jean-Claude Voegel. This method is applied in many laboratories world-wide in various scientific disciplines, including chemistry, materials science and biotechnology. Gero Decher has received numerous awards, including the ECIS-Rhodia prize in 2010 and the Grand Prix of the French "Academie des Sciences" for Nanobiotechnology in 2009. Joseph B. Schlenoff is Mandelkern Professor of Polymer Science of the Department of Chemistry and Biochemistry at the Florida State University, USA. His laboratory is engaged in multidisciplinary research centered on the use of novel structures made from polyelectrolytes that are deposited using the layer-by-layer technique. His work, supported by the National Science Foundation and the National Institutes of Health, among others, focuses on fundamental polymer science aspects of polyelectrolyte complexes and on their interactions with biological materials. In 2011, Joseph Schlenoff received a Gutenburg Chair at the University of Strasbourg.